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Enantiomeric Discrimination by Surface- Enhanced Raman Scattering- Chiral Anisotropy of Chiral Nanostructured Gold Films
dc.contributor.authorLiu, Zexi
dc.contributor.authorAi, Jing
dc.contributor.authorKumar, Prashant
dc.contributor.authorYou, Enming
dc.contributor.authorZhou, Xiong
dc.contributor.authorLiu, Xi
dc.contributor.authorTian, Zhongqun
dc.contributor.authorBouř, Petr
dc.contributor.authorDuan, Yingying
dc.contributor.authorHan, Lu
dc.contributor.authorKotov, Nicholas A.
dc.contributor.authorDing, Songyuan
dc.contributor.authorChe, Shunai
dc.date.accessioned2020-09-02T14:57:41Z
dc.date.availableWITHHELD_12_MONTHS
dc.date.available2020-09-02T14:57:41Z
dc.date.issued2020-08-24
dc.identifier.citationLiu, Zexi; Ai, Jing; Kumar, Prashant; You, Enming; Zhou, Xiong; Liu, Xi; Tian, Zhongqun; Bouř, Petr ; Duan, Yingying; Han, Lu; Kotov, Nicholas A.; Ding, Songyuan; Che, Shunai (2020). "Enantiomeric Discrimination by Surface- Enhanced Raman Scattering- Chiral Anisotropy of Chiral Nanostructured Gold Films." Angewandte Chemie International Edition 59(35): 15226-15231.
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttps://hdl.handle.net/2027.42/156417
dc.description.abstractA surface- enhanced Raman scattering- chiral anisotropy (SERS- ChA) effect is reported that combines chiral discrimination and surface Raman scattering enhancement on chiral nanostructured Au films (CNAFs) equipped in the normal Raman scattering Spectrometer. The CNAFs provided remarkably higher enhancement factors of Raman scattering (EFs) for particular enantiomers, and the SERS intensity was proportional to the enantiomeric excesses (ee) values. Except for molecules with mesomeric species, all of the tested enantiomers exhibited high SERS- ChA asymmetry factors (g), ranging between 1.34 and 1.99 regardless of polarities, sizes, chromophores, concentrations and ee. The effect might be attributed to selective resonance coupling between the induced electric and magnetic dipoles associated with enantiomers and chiral plasmonic modes of CNAFs.Absolution by SERS: A surface- enhanced Raman scattering chiral anisotropy effect is presented that combines chiral discrimination and surface Raman scattering enhancement on chiral nanostructured Au films. It is applied in the normal Raman scattering system to identify the absolute configuration and composition of enantiomers, overcoming disadvantages of polarimeter systems and chromatography.
dc.publisherWiley Periodicals, Inc.
dc.publisherCambridge University Press
dc.subject.otherchiral anisotropy
dc.subject.otherchiral nanostructured Au film
dc.subject.otherchiral response
dc.subject.otherenantiomeric discrimination
dc.subject.othersurface-enhanced Raman scattering
dc.titleEnantiomeric Discrimination by Surface- Enhanced Raman Scattering- Chiral Anisotropy of Chiral Nanostructured Gold Films
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelChemistry
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/156417/3/anie202006486-sup-0001-misc_information.pdfen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/156417/2/anie202006486_am.pdfen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/156417/1/anie202006486.pdfen_US
dc.identifier.doi10.1002/anie.202006486
dc.identifier.sourceAngewandte Chemie International Edition
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