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Clumped‐Isotope Geothermometry and Carbonate U–Pb Geochronology of the Alta Stock Metamorphic Aureole, Utah, USA: Insights on the Kinetics of Metamorphism in Carbonates
dc.contributor.authorBrenner, Dana C.
dc.contributor.authorPassey, Benjamin H.
dc.contributor.authorHolder, Robert M.
dc.contributor.authorViete, Daniel R.
dc.date.accessioned2021-04-06T02:15:12Z
dc.date.available2022-05-05 22:15:03en
dc.date.available2021-04-06T02:15:12Z
dc.date.issued2021-04
dc.identifier.citationBrenner, Dana C.; Passey, Benjamin H.; Holder, Robert M.; Viete, Daniel R. (2021). "Clumped‐Isotope Geothermometry and Carbonate U–Pb Geochronology of the Alta Stock Metamorphic Aureole, Utah, USA: Insights on the Kinetics of Metamorphism in Carbonates." Geochemistry, Geophysics, Geosystems 22(4): n/a-n/a.
dc.identifier.issn1525-2027
dc.identifier.issn1525-2027
dc.identifier.urihttps://hdl.handle.net/2027.42/167127
dc.description.abstractTo assess thermal and kinetic influences on atomic mobility and mineral (neo)crystallization, clumped‐isotope abundances of calcite and dolomite were measured alongside dolomite cation ordering and U–Pb dates, across metamorphic grade within the c. 35–30 Ma Alta stock contact metamorphic aureole, Utah, USA. Average Δ47 values of dolomite inside the metamorphic aureole reflect the blocking temperature of dolomite (300°C–350°C) during cooling from peak temperatures. Dolomite Δ47 values outside the metamorphic aureole record a temperature of ∼160°C. At the talc isograd, dolomite Δ47 values abruptly change, corresponding to a decrease of ∼180°C over <50 m in the down‐temperature direction. This observed step in dolomite Δ47 values does not correlate with cation ordering in dolomite or U–Pb dates, neither of which correlate well with metamorphic grade. The short distance over which dolomite Δ47 values change indicates strong temperature sensitivity in the kinetics of dolomite clumped‐isotope reordering, and is consistent with a wide range of clumped‐isotope reequilibration modeling results. We hypothesize that clumped‐isotope reordering in dolomite precedes more extensive recrystallization or metamorphic reaction, such as the formation of talc. Dolomite U–Pb analyses from inside and outside the metamorphic aureole populate a single discordia ∼60 Myr younger than depositional age (Mississippian), recording resetting in response to some older postdepositional, but premetamorphic process.Key Points:Dolomite clumped isotopes record an abrupt ∼180°C decrease, over <50 m, at the talc isograd of the Alta contact metamorphic aureoleThis step feature suggests strong thermal sensitivity in clumped‐isotope reordering that precedes talc neocrystallizationClumped‐isotope geothermometry may provide new insights into processes controlling metamorphism and reaction kinetics in carbonates
dc.publisherUnited States Geological Survey
dc.publisherWiley Periodicals, Inc.
dc.subject.othercontact metamorphism
dc.subject.otherkinetics
dc.subject.otherclumped‐isotope geothermometry
dc.subject.othercarbonate U–Pb geochronology
dc.subject.othercarbonate
dc.titleClumped‐Isotope Geothermometry and Carbonate U–Pb Geochronology of the Alta Stock Metamorphic Aureole, Utah, USA: Insights on the Kinetics of Metamorphism in Carbonates
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelGeological Sciences
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/167127/1/ggge22474.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/167127/2/2020GC009238-sup-0001-Supporting_Information_SI-S01.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/167127/3/ggge22474_am.pdf
dc.identifier.doi10.1029/2020GC009238
dc.identifier.sourceGeochemistry, Geophysics, Geosystems
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