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InterCarb: A Community Effort to Improve Interlaboratory Standardization of the Carbonate Clumped Isotope Thermometer Using Carbonate Standards
dc.contributor.authorBernasconi, S. M.
dc.contributor.authorDaëron, M.
dc.contributor.authorBergmann, K. D.
dc.contributor.authorBonifacie, M.
dc.contributor.authorMeckler, A. N.
dc.contributor.authorAffek, H. P.
dc.contributor.authorAnderson, N.
dc.contributor.authorBajnai, D.
dc.contributor.authorBarkan, E.
dc.contributor.authorBeverly, E.
dc.contributor.authorBlamart, D.
dc.contributor.authorBurgener, L.
dc.contributor.authorCalmels, D.
dc.contributor.authorChaduteau, C.
dc.contributor.authorClog, M.
dc.contributor.authorDavidheiser‐kroll, B.
dc.contributor.authorDavies, A.
dc.contributor.authorDux, F.
dc.contributor.authorEiler, J.
dc.contributor.authorElliott, B.
dc.contributor.authorFetrow, A. C.
dc.contributor.authorFiebig, J.
dc.contributor.authorGoldberg, S.
dc.contributor.authorHermoso, M.
dc.contributor.authorHuntington, K. W.
dc.contributor.authorHyland, E.
dc.contributor.authorIngalls, M.
dc.contributor.authorJaggi, M.
dc.contributor.authorJohn, C. M.
dc.contributor.authorJost, A. B.
dc.contributor.authorKatz, S.
dc.contributor.authorKelson, J.
dc.contributor.authorKluge, T.
dc.contributor.authorKocken, I. J.
dc.contributor.authorLaskar, A.
dc.contributor.authorLeutert, T. J.
dc.contributor.authorLiang, D.
dc.contributor.authorLucarelli, J.
dc.contributor.authorMackey, T. J.
dc.contributor.authorMangenot, X.
dc.contributor.authorMeinicke, N.
dc.contributor.authorModestou, S. E.
dc.contributor.authorMüller, I. A.
dc.contributor.authorMurray, S.
dc.contributor.authorNeary, A.
dc.contributor.authorPackard, N.
dc.contributor.authorPassey, B. H.
dc.contributor.authorPelletier, E.
dc.contributor.authorPetersen, S.
dc.contributor.authorPiasecki, A.
dc.contributor.authorSchauer, A.
dc.contributor.authorSnell, K. E.
dc.contributor.authorSwart, P. K.
dc.contributor.authorTripati, A.
dc.contributor.authorUpadhyay, D.
dc.contributor.authorVennemann, T.
dc.contributor.authorWinkelstern, I.
dc.contributor.authorYarian, D.
dc.contributor.authorYoshida, N.
dc.contributor.authorZhang, N.
dc.contributor.authorZiegler, M.
dc.date.accessioned2021-06-02T21:08:08Z
dc.date.available2022-06-02 17:08:06en
dc.date.available2021-06-02T21:08:08Z
dc.date.issued2021-05
dc.identifier.citationBernasconi, S. M.; Daëron, M. ; Bergmann, K. D.; Bonifacie, M.; Meckler, A. N.; Affek, H. P.; Anderson, N.; Bajnai, D.; Barkan, E.; Beverly, E.; Blamart, D.; Burgener, L.; Calmels, D.; Chaduteau, C.; Clog, M.; Davidheiser‐kroll, B. ; Davies, A.; Dux, F.; Eiler, J.; Elliott, B.; Fetrow, A. C.; Fiebig, J.; Goldberg, S.; Hermoso, M.; Huntington, K. W.; Hyland, E.; Ingalls, M.; Jaggi, M.; John, C. M.; Jost, A. B.; Katz, S.; Kelson, J.; Kluge, T.; Kocken, I. J.; Laskar, A.; Leutert, T. J.; Liang, D.; Lucarelli, J.; Mackey, T. J.; Mangenot, X.; Meinicke, N.; Modestou, S. E.; Müller, I. A. ; Murray, S.; Neary, A.; Packard, N.; Passey, B. H.; Pelletier, E.; Petersen, S.; Piasecki, A.; Schauer, A.; Snell, K. E.; Swart, P. K.; Tripati, A.; Upadhyay, D.; Vennemann, T.; Winkelstern, I.; Yarian, D.; Yoshida, N.; Zhang, N.; Ziegler, M. (2021). "InterCarb: A Community Effort to Improve Interlaboratory Standardization of the Carbonate Clumped Isotope Thermometer Using Carbonate Standards." Geochemistry, Geophysics, Geosystems 22(5): n/a-n/a.
dc.identifier.issn1525-2027
dc.identifier.issn1525-2027
dc.identifier.urihttps://hdl.handle.net/2027.42/167811
dc.description.abstractIncreased use and improved methodology of carbonate clumped isotope thermometry has greatly enhanced our ability to interrogate a suite of Earth- system processes. However, interlaboratory discrepancies in quantifying carbonate clumped isotope (Π47) measurements persist, and their specific sources remain unclear. To address interlaboratory differences, we first provide consensus values from the clumped isotope community for four carbonate standards relative to heated and equilibrated gases with 1,819 individual analyses from 10 laboratories. Then we analyzed the four carbonate standards along with three additional standards, spanning a broad range of δ47 and Π47 values, for a total of 5,329 analyses on 25 individual mass spectrometers from 22 different laboratories. Treating three of the materials as known standards and the other four as unknowns, we find that the use of carbonate reference materials is a robust method for standardization that yields interlaboratory discrepancies entirely consistent with intralaboratory analytical uncertainties. Carbonate reference materials, along with measurement and data processing practices described herein, provide the carbonate clumped isotope community with a robust approach to achieve interlaboratory agreement as we continue to use and improve this powerful geochemical tool. We propose that carbonate clumped isotope data normalized to the carbonate reference materials described in this publication should be reported as Π47 (I- CDES) values for Intercarb- Carbon Dioxide Equilibrium Scale.Key PointsThe exclusive use of carbonate reference materials is a robust method for the standardization of clumped isotope measurementsMeasurements using different acid temperatures, designs of preparation lines, and mass spectrometers are statistically indistinguishableWe propose new consensus values for a set of seven carbonate reference materials and updated guidelines to report clumped isotope measurements
dc.publisherWiley Periodicals, Inc.
dc.subject.othercarbonate
dc.subject.otherreference materials
dc.subject.othermass spectrometry
dc.subject.otherinterlaboratory calibration
dc.subject.otherclumped isotopes
dc.titleInterCarb: A Community Effort to Improve Interlaboratory Standardization of the Carbonate Clumped Isotope Thermometer Using Carbonate Standards
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelGeological Sciences
dc.subject.hlbtoplevelScience
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/167811/1/ggge22508.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/167811/2/ggge22508_am.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/167811/3/2020GC009588-sup-0001-Supporting_Information_SI-S01.pdf
dc.identifier.doi10.1029/2020GC009588
dc.identifier.sourceGeochemistry, Geophysics, Geosystems
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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