Scalable Synthesis of Monolayer Hexagonal Boron Nitride on Graphene with Giant Bandgap Renormalization
dc.contributor.author | Wang, Ping | |
dc.contributor.author | Lee, Woncheol | |
dc.contributor.author | Corbett, Joseph P. | |
dc.contributor.author | Koll, William H. | |
dc.contributor.author | Vu, Nguyen M. | |
dc.contributor.author | Laleyan, David Arto | |
dc.contributor.author | Wen, Qiannan | |
dc.contributor.author | Wu, Yuanpeng | |
dc.contributor.author | Pandey, Ayush | |
dc.contributor.author | Gim, Jiseok | |
dc.contributor.author | Wang, Ding | |
dc.contributor.author | Qiu, Diana Y. | |
dc.contributor.author | Hovden, Robert | |
dc.contributor.author | Kira, Mackillo | |
dc.contributor.author | Heron, John T. | |
dc.contributor.author | Gupta, Jay A. | |
dc.contributor.author | Kioupakis, Emmanouil | |
dc.contributor.author | Mi, Zetian | |
dc.date.accessioned | 2022-06-01T20:29:56Z | |
dc.date.available | 2023-06-01 16:29:53 | en |
dc.date.available | 2022-06-01T20:29:56Z | |
dc.date.issued | 2022-05 | |
dc.identifier.citation | Wang, Ping; Lee, Woncheol; Corbett, Joseph P.; Koll, William H.; Vu, Nguyen M.; Laleyan, David Arto; Wen, Qiannan; Wu, Yuanpeng; Pandey, Ayush; Gim, Jiseok; Wang, Ding; Qiu, Diana Y.; Hovden, Robert; Kira, Mackillo; Heron, John T.; Gupta, Jay A.; Kioupakis, Emmanouil; Mi, Zetian (2022). "Scalable Synthesis of Monolayer Hexagonal Boron Nitride on Graphene with Giant Bandgap Renormalization." Advanced Materials 34(21): n/a-n/a. | |
dc.identifier.issn | 0935-9648 | |
dc.identifier.issn | 1521-4095 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/172829 | |
dc.description.abstract | Monolayer hexagonal boron nitride (hBN) has been widely considered a fundamental building block for 2D heterostructures and devices. However, the controlled and scalable synthesis of hBN and its 2D heterostructures has remained a daunting challenge. Here, an hBN/graphene (hBN/G) interface-mediated growth process for the controlled synthesis of high-quality monolayer hBN is proposed and further demonstrated. It is discovered that the in-plane hBN/G interface can be precisely controlled, enabling the scalable epitaxy of unidirectional monolayer hBN on graphene, which exhibits a uniform moir� superlattice consistent with single-domain hBN, aligned to the underlying graphene lattice. Furthermore, it is identified that the deep-ultraviolet emission at 6.12�eV stems from the 1s-exciton state of monolayer hBN with a giant renormalized direct bandgap on graphene. This work provides a viable path for the controlled synthesis of ultraclean, wafer-scale, atomically ordered 2D quantum materials, as well as the fabrication of 2D quantum electronic and optoelectronic devices.Controllable synthesis of monolayer hexagonal boron nitride (hBN) has remained a daunting challenge. An hBN/graphene-interface-mediated growth concept to enable scalable epitaxy of unidirectional high-quality monolayer hBN on graphene substrates is proposed and demonstrated. A uniform moir� superlattice and robust deep-ultraviolet excitonic emission (around 6.12 eV) are achieved in such a monolayer hBN/graphene van der Waals heterostructure. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | moir� superlattices | |
dc.subject.other | monolayer hexagonal boron nitride | |
dc.subject.other | 2D heterostructures | |
dc.subject.other | bandgap | |
dc.subject.other | graphene | |
dc.title | Scalable Synthesis of Monolayer Hexagonal Boron Nitride on Graphene with Giant Bandgap Renormalization | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbsecondlevel | Engineering (General) | |
dc.subject.hlbtoplevel | Engineering | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/172829/1/adma202201387_am.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/172829/2/adma202201387-sup-0001-SuppMat.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/172829/3/adma202201387.pdf | |
dc.identifier.doi | 10.1002/adma.202201387 | |
dc.identifier.source | Advanced Materials | |
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dc.working.doi | NO | en |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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