Synergetic Anion–Cation Redox Ensures a Highly Stable Layered Cathode for Sodium-Ion Batteries
dc.contributor.author | Li, Xiang | |
dc.contributor.author | Xu, Jialiang | |
dc.contributor.author | Li, Haoyu | |
dc.contributor.author | Zhu, Hong | |
dc.contributor.author | Guo, Shaohua | |
dc.contributor.author | Zhou, Haoshen | |
dc.date.accessioned | 2022-07-05T21:02:37Z | |
dc.date.available | 2023-06-05 17:02:35 | en |
dc.date.available | 2022-07-05T21:02:37Z | |
dc.date.issued | 2022-05 | |
dc.identifier.citation | Li, Xiang; Xu, Jialiang; Li, Haoyu; Zhu, Hong; Guo, Shaohua; Zhou, Haoshen (2022). "Synergetic Anion–Cation Redox Ensures a Highly Stable Layered Cathode for Sodium-Ion Batteries." Advanced Science 9(16): n/a-n/a. | |
dc.identifier.issn | 2198-3844 | |
dc.identifier.issn | 2198-3844 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/173003 | |
dc.description.abstract | Sodium-ion batteries are commonly regarded as a promising candidate in large-scale energy storage. Layered iron/manganese oxide cathodes receive extensive attentions due to the element abundance and large theoretical capacity. However, these materials usually undergo obvious degradation of electrochemical performance due to the tendency of Mn dissolution and Fe migration during continuous sodium release and uptake. Herein, a strategy of anion–cation synergetic redox is proposed to suppress the structural deterioration originated from overusing the electrochemical activity of transition-metal ions, and decreased lattice strain as well as superior electrochemical performance are realized simultaneously. Results show that the Na0.8Li0.2Fe0.2Mn0.6O2 (NLFM) electrode is highly resistant to the erosion of moisture that is distinct from the traditional Mn/Fe-based electrodes. Moreover, the NLFM electrode demonstrates solid solution behavior without phase transition during cycles. The ultra-small volume change of 0.85% is ascribed to the negligible manganese dissolution and invisible transition-metal migration. The high-stable layered structure assures superior reversible capacity of ≈165 mA h g–1, excellent rate capability, and splendid capacity retention of over 98.3% with 100 cycles. The findings deepen the understanding of the synergy between anion and cation redox and provide new insights to design the high-stable layered cathode for sodium-ion batteries.A strategy of anion–cation synergetic redox is proposed to suppress the structural deterioration of sodium-ion layered Fe/Mn-based cathodes. The electrode is of high resistance to the erosion of moisture that is distinct from the traditional electrodes. Moreover, the electrode demonstrates solid solution behavior without phase transition during cycles. The ultra-small volume change of 0.85% is ascribed to the negligible manganese dissolution and invisible Fe migration. The high-stable layered structure assures superior reversible capacity and excellent rate capability. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | sodium-ion batteries | |
dc.subject.other | suppressed phase transition | |
dc.subject.other | high-stable layered cathodes | |
dc.subject.other | anion redox | |
dc.title | Synergetic Anion–Cation Redox Ensures a Highly Stable Layered Cathode for Sodium-Ion Batteries | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbtoplevel | Engineering | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/173003/1/advs3834.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/173003/2/advs3834_am.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/173003/3/advs3834-sup-0001-SuppMat.pdf | |
dc.identifier.doi | 10.1002/advs.202105280 | |
dc.identifier.source | Advanced Science | |
dc.identifier.citedreference | K. Momma, F. Izumi, J. Appl. Crystallogr. 2011, 44, 1272. | |
dc.identifier.citedreference | Y. Qiao, S. Guo, K. Zhu, P. Liu, X. Li, K. Jiang, C.-J. Sun, M. Chen, H. Zhou, Energy Environ. Sci. 2018, 11, 299. | |
dc.identifier.citedreference | X. Li, Y. Qiao, S. Guo, Z. Xu, H. Zhu, X. Zhang, Y. Yuan, P. He, M. Ishida, H. Zhou, Adv. Mater. 2018, 30, 1705197. | |
dc.identifier.citedreference | X. Li, Y. Qiao, S. Guo, K. Jiang, M. Ishida, H. Zhou, Adv. Mater. 2019, 31, 1807825. | |
dc.identifier.citedreference | X. Rong, E. Hu, Y. Lu, F. Meng, C. Zhao, X. Wang, Q. Zhang, X. Yu, L. Gu, Y.-S. Hu, H. Li, X. Huang, X.-Q. Yang, C. Delmas, L. Chen, Joule 2019, 3, 503. | |
dc.identifier.citedreference | B. He, P. H. Mi, A. J. Ye, S. T. Chi, Y. Jiao, L. W. Zhang, B. W. Pu, Z. Y. Zou, W. Q. Zhang, M. Avdeev, S. Adams, J. T. Zhao, S. Q. Shi, Acta Mater. 2021, 203, 116490. | |
dc.identifier.citedreference | D. H. Seo, J. Lee, A. Urban, R. Malik, S. Kang, G. Ceder, Nat. Chem. 2016, 8, 692. | |
dc.identifier.citedreference | J. Hong, W. E. Gent, P. Xiao, K. Lim, D.-H. Seo, J. Wu, P. M. Csernica, C. J. Takacs, D. Nordlund, C.-J. Sun, K. H. Stone, D. Passarello, W. Yang, D. Prendergast, G. Ceder, M. F. Toney, W. C. Chueh, Nat. Mater. 2019, 18, 256. | |
dc.identifier.citedreference | M. Okubo, A. Yamada, ACS Appl. Mater. Interfaces 2017, 9, 36463. | |
dc.identifier.citedreference | A. C. Larson, R. B. Von Dreele, Los Alamos National Laboratory Report LAUR 1994, 86. | |
dc.identifier.citedreference | B. H. Toby, J. Appl. Crystallogr. 2001, 34, 210. | |
dc.identifier.citedreference | C. Delmas, C. Fouassier, P. Hagenmuller, Physica B+C 1980, 99, 81. | |
dc.identifier.citedreference | M. Jiang, B. Key, Y. S. Meng, C. P. Grey, Chem. Mater. 2009, 21, 2733. | |
dc.identifier.citedreference | B. Xu, C. R. Fell, M. Chi, Y. S. Meng, Energy Environ. Sci. 2011, 4, 2223. | |
dc.identifier.citedreference | A. R. Armstrong, M. Holzapfel, P. Novak, C. S. Johnson, S. H. Kang, M. M. Thackeray, P. G. Bruce, J. Am. Chem. Soc. 2006, 128, 8694. | |
dc.identifier.citedreference | C. Chen, W. Y. Huang, Y. W. Li, M. J. Zhang, K. Q. Nie, J. O. Wang, W. G. Zhao, R. Qi, C. J. Zuo, Z. B. Li, H. C. Yi, F. Pan, Nano Energy 2021, 90, 106504. | |
dc.identifier.citedreference | Q. Wang, S. Mariyappan, G. Rousse, A. V. Morozov, B. Porcheron, R. Dedryvere, J. P. Wu, W. L. Yang, L. T. Zhang, M. Chakir, M. Avdeev, M. Deschamps, Y. S. Yu, J. Cabana, M. L. Doublet, A. M. Abakumov, J. M. Tarascon, Nat. Mater. 2021, 20, 353. | |
dc.identifier.citedreference | C. Johnson, J. Kim, C. Lefief, N. Li, J. Vaughey, M. Thackeray, Electrochem. Commun. 2004, 6, 1085. | |
dc.identifier.citedreference | E. McCalla, A. M. Abakumov, M. Saubanere, D. Foix, E. J. Berg, G. Rousse, M. L. Doublet, D. Gonbeau, P. Novak, G. Van Tendeloo, R. Dominko, J. M. Tarascon, Science 2015, 350, 1516. | |
dc.identifier.citedreference | M. Sathiya, A. M. Abakumov, D. Foix, G. Rousse, K. Ramesha, M. Saubanere, M. L. Doublet, H. Vezin, C. P. Laisa, A. S. Prakash, D. Gonbeau, G. VanTendeloo, J. M. Tarascon, Nat. Mater. 2015, 14, 230. | |
dc.identifier.citedreference | M. Sathiya, G. Rousse, K. Ramesha, C. P. Laisa, H. Vezin, M. T. Sougrati, M. L. Doublet, D. Foix, D. Gonbeau, W. Walker, A. S. Prakash, M. Ben Hassine, L. Dupont, J. M. Tarascon, Nat. Mater. 2013, 12, 827. | |
dc.identifier.citedreference | N. Yabuuchi, M. Takeuchi, M. Nakayama, H. Shiiba, M. Ogawa, K. Nakayama, T. Ohta, D. Endo, T. Ozaki, T. Inamasu, K. Sato, S. Komaba, Proc. Natl. Acad. Sci. 2015, 112, 7650. | |
dc.identifier.citedreference | K. Luo, M. R. Roberts, R. Hao, N. Guerrini, D. M. Pickup, Y.-S. Liu, K. Edström, J. Guo, A. V. Chadwick, L. C. Duda, P. G. Bruce, Nat. Chem. 2016, 8, 684. | |
dc.identifier.citedreference | L. Li, E. Lee, J. W. Freeland, T. T. Fister, M. M. Thackeray, M. K. Chan, J. Phys. Chem. Lett. 2019, 10, 806. | |
dc.identifier.citedreference | J. Lee, J. K. Papp, R. J. Clément, S. Sallis, D. H. Kwon, T. Shi, W. Yang, B. D. McCloskey, G. Ceder, Nat. Commun. 2017, 8, 981. | |
dc.identifier.citedreference | M. M. Thackeray, C. S. Johnson, J. T. Vaughey, N. Li, S. A. Hackney, J. Mater. Chem. 2005, 15, 2257. | |
dc.identifier.citedreference | J. Roos, C. Eames, S. M. Wood, A. Whiteside, M. Saiful Islam, Phys. Chem. Chem. Phys. 2015, 17, 22259. | |
dc.identifier.citedreference | S. Guo, Q. Li, P. Liu, M. Chen, H. Zhou, Nat. Commun. 2017, 8, 135. | |
dc.identifier.citedreference | N. Yabuuchi, H. Yoshida, S. Komaba, Electrochemistry 2012, 80, 716. | |
dc.identifier.citedreference | S. Komaba, C. Takei, T. Nakayama, A. Ogata, N. Yabuuchi, Electrochem. Commun. 2010, 12, 355. | |
dc.identifier.citedreference | S. Guo, H. Yu, P. Liu, Y. Ren, T. Zhang, M. Chen, M. Ishida, H. Zhou, Energy Environ. Sci. 2015, 8, 1237. | |
dc.identifier.citedreference | S. Kikkawa, S. Miyazaki, M. Koizumi, J. Solid State Chem. 1986, 62, 35. | |
dc.identifier.citedreference | A. Caballero, L. Hernan, J. Morales, L. Sanchez, J. S. Pena, M. Aranda, J. Mater. Chem. 2002, 12, 1142. | |
dc.identifier.citedreference | C. Delmas, J.-J. Braconnier, C. Fouassier, P. Hagenmuller, Solid State Ionics 1981, 3, 165. | |
dc.identifier.citedreference | N. Yabuuchi, M. Kajiyama, J. Iwatate, H. Nishikawa, S. Hitomi, R. Okuyama, R. Usui, Y. Yamada, S. Komaba, Nat. Mater. 2012, 11, 512. | |
dc.identifier.citedreference | S. Guo, P. Liu, Y. Sun, K. Zhu, J. Yi, M. Chen, M. Ishida, H. Zhou, Angew. Chem., Int. Ed. 2015, 54, 11701. | |
dc.identifier.citedreference | S. Guo, Y. Sun, J. Yi, K. Zhu, P. Liu, Y. Zhu, G. Zhu, M. Chen, M. Ishida, H. Zhou, NPG Asia Mater 2016, 8, e266. | |
dc.identifier.citedreference | N. Yabuuchi, S. Komaba, Sci. Technol. Adv. Mater. 2014, 15, 043501. | |
dc.identifier.citedreference | S. Xu, J. Wu, E. Hu, Q. Li, J. Zhang, Y. Wang, E. Stavitski, L. Jiang, X. Rong, X. Yu, J. Mater. Chem. A 2018, 6, 20795. | |
dc.identifier.citedreference | P. F. Wang, Y. You, Y. X. Yin, Y. S. Wang, L. J. Wan, L. Gu, Y. G. Guo, Angew. Chem., Int. Ed. 2016, 55, 7445. | |
dc.identifier.citedreference | V. Duffort, E. Talaie, R. Black, L. F. Nazar, Chem. Mater. 2015, 27, 2515. | |
dc.identifier.citedreference | S. H. Guo, Y. Sun, P. Liu, J. Yi, P. He, X. Y. Zhang, Y. B. Zhu, R. Senga, K. Suenaga, M. W. Chen, H. S. Zhou, Sci. Bull. 2018, 63, 376. | |
dc.working.doi | NO | en |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.