Ion/Electron Redistributed 3D Flexible Host for Achieving Highly Reversible Li Metal Batteries
dc.contributor.author | Jiang, Huai | |
dc.contributor.author | Zhou, Yangen | |
dc.contributor.author | Guan, Caohong | |
dc.contributor.author | Bai, Maohui | |
dc.contributor.author | Qin, Furong | |
dc.contributor.author | Yi, Maoyi | |
dc.contributor.author | Li, Jie | |
dc.contributor.author | Hong, Bo | |
dc.contributor.author | Lai, Yanqing | |
dc.date.accessioned | 2022-08-02T18:58:05Z | |
dc.date.available | 2023-08-02 14:58:03 | en |
dc.date.available | 2022-08-02T18:58:05Z | |
dc.date.issued | 2022-07 | |
dc.identifier.citation | Jiang, Huai; Zhou, Yangen; Guan, Caohong; Bai, Maohui; Qin, Furong; Yi, Maoyi; Li, Jie; Hong, Bo; Lai, Yanqing (2022). "Ion/Electron Redistributed 3D Flexible Host for Achieving Highly Reversible Li Metal Batteries." Small 18(29): n/a-n/a. | |
dc.identifier.issn | 1613-6810 | |
dc.identifier.issn | 1613-6829 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/173123 | |
dc.description.abstract | 3D carbon frameworks are promising hosts to achieve highly reversible lithium (Li) metal anodes, whereas insufficient effects are attributed to their single electron conductivity causing local aggregating of electron/Li+ and uncontrollable Li dendrites. Herein, an ion/electron redistributed 3D flexible host is designed by lithiophilic carbon fiber cloth (CFC) modified with metal–organic framework (MOF)-derived porous carbon sheath with embedded CoP nanoparticles (CoP-C@CFC). Theory calculations demonstrate the strong binding energy and plenty of charge transfer from the reaction between CoP and Li atom are presented, which is beneficial to in situ construct a Li3P@Co ion/electron conductive interface on every single CoP-C@CFC. Thanks to the high ionic conductive Li3P and electron-conductive Co nanoparticles, the rapid dispersion of Li+ and obviously reduced local current density can be achieved simultaneously. Furthermore, in situ optical microscopy observations display obvious depression for volume expansion and Li dendrites. As expected, a miraculous average Coulombic efficiency (CE) of 99.96% over 1100 cycles at 3 mA cm-2 and a low overpotential of 11.5 mV with prolonged cycling of over 3200 h at 20% depth of discharge are successfully obtained. Consequently, the CoP-C@CFC-Li||LiFePO4 full cells maintain a capacity retention of 95.8% with high CE of 99.96% over 500 cycles at 2 C and excellent rate capability.An ion/electron redistributed 3D flexible host is designed by lithiophilic carbon fiber cloth modified with MOF-derived porous carbon sheath with embedded CoP nanoparticles (CoP-C@CFC). During the Li plating, the in situ formed Li3P@Co conductive interface on CoP-C@CFC realizes Li+/charge redistribution, which achieves highly average Coulombic efficiency of 99.96% over 1100 cycles at practical current density of 3 mA cm−2. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | cobalt phosphide (CoP) nanoparticles | |
dc.subject.other | ion/electron redistribution | |
dc.subject.other | lithium metal anodes | |
dc.subject.other | metal–organic frameworks | |
dc.subject.other | high reversibility | |
dc.title | Ion/Electron Redistributed 3D Flexible Host for Achieving Highly Reversible Li Metal Batteries | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbsecondlevel | Physics | |
dc.subject.hlbtoplevel | Engineering | |
dc.subject.hlbtoplevel | Science | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/173123/1/smll202107641_am.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/173123/2/smll202107641.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/173123/3/smll202107641-sup-0001-SuppMat.pdf | |
dc.identifier.doi | 10.1002/smll.202107641 | |
dc.identifier.source | Small | |
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dc.working.doi | NO | en |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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