Unique Dimerization Topology and Countercation Binding Modes in 12-Metallacrown-4 Compounds
dc.contributor.author | Salerno, Elvin V. | |
dc.contributor.author | Foley, Collin M. | |
dc.contributor.author | Marzaroli, Vittoria | |
dc.contributor.author | Schneider, Bernadette L. | |
dc.contributor.author | Sharin, Max D. | |
dc.contributor.author | Kampf, Jeff W. | |
dc.contributor.author | Marchiò, Luciano | |
dc.contributor.author | Zeller, Matthias | |
dc.contributor.author | Guillot, Régis | |
dc.contributor.author | Mallah, Talal | |
dc.contributor.author | Tegoni, Matteo | |
dc.contributor.author | Pecoraro, Vincent L. | |
dc.contributor.author | Zaleski, Curtis M. | |
dc.date.accessioned | 2022-12-05T16:41:05Z | |
dc.date.available | 2023-12-05 11:41:02 | en |
dc.date.available | 2022-12-05T16:41:05Z | |
dc.date.issued | 2022-11-17 | |
dc.identifier.citation | Salerno, Elvin V.; Foley, Collin M.; Marzaroli, Vittoria; Schneider, Bernadette L.; Sharin, Max D.; Kampf, Jeff W.; Marchiò, Luciano ; Zeller, Matthias; Guillot, Régis ; Mallah, Talal; Tegoni, Matteo; Pecoraro, Vincent L.; Zaleski, Curtis M. (2022). "Unique Dimerization Topology and Countercation Binding Modes in 12- Metallacrown- 4 Compounds." European Journal of Inorganic Chemistry 2022(32): n/a-n/a. | |
dc.identifier.issn | 1434-1948 | |
dc.identifier.issn | 1099-0682 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/175227 | |
dc.description.abstract | Seven dimeric metallacrowns (MC) based on Ln[12-MCM(III)N(shi)-4], where LnIII=Dy, Ho, Yb, or Y, MIII=Mn or Ga, and shi3− is salicylhydroximate, have been synthesized and characterized by single-crystal X-ray diffraction, and for the dysprosium-manganese dimers, the magnetic properties have been measured. In each dimer two Ln[12-MCM(III)N(shi)-4] units are linked by four bridging dicarboxylate anions (isophthalate, trimesate, dinicotinate, or 2,2′-dithiodibenzoate). Three different countercations (sodium, gallium(III), or pyridinium) were used to maintain charge balance of the dimer. While pyridinium does not bind to the dimer, the choice of the dicarboxylate dictates where the countercations Na+ or GaIII bind. With isophthalate and trimesate, the sodium ion binds to the central MC cavity opposite of the LnIII, and with dinicotinate the sodium or gallium(III) ions bind to the pyridyl nitrogen of the dinicotinate. All three Dy2Mn8 dimers exhibit an out-of-phase magnetic susceptibility signal consistent with a shallow barrier to magnetization relaxation.The structures of seven dimeric heterometallic metallacrowns are described. Each dimer consists of two 12-metallacrown-4 units (ring metals Mn3+ or Ga3+) linked together by dicarboxylate anions (isophthalate, trimesate, dinicotinate, or 2,2′-dithiodibenzoate). Each metallacrown unit also contains one lanthanide ion bound to the central cavity. Lastly, the magnetism of the dysprosium-manganese dimers is examined, and each display slow magnetic relaxation. | |
dc.publisher | Wiley-VCH Verlap & Co. KGaA | |
dc.subject.other | Metallacrowns | |
dc.subject.other | Heterometallic complexes | |
dc.subject.other | Lanthanides | |
dc.subject.other | Magnetic properties | |
dc.subject.other | Supramolecular chemistry | |
dc.title | Unique Dimerization Topology and Countercation Binding Modes in 12-Metallacrown-4 Compounds | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Chemical Engineering | |
dc.subject.hlbsecondlevel | Chemistry | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbtoplevel | Engineering | |
dc.subject.hlbtoplevel | Science | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/175227/1/ejic202200439_am.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/175227/2/ejic202200439.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/175227/3/ejic202200439-sup-0001-misc_information.pdf | |
dc.identifier.doi | 10.1002/ejic.202200439 | |
dc.identifier.source | European Journal of Inorganic Chemistry | |
dc.identifier.citedreference | M. Perovic, V. Kusigerski, V. Spasojevic, A. Mrakovic, J. Blanusa, M. Zentkova, M. Mihalik, J. Phys. D 2013, 46, 165001. | |
dc.identifier.citedreference | C. M. Foley, M. A. Armanious, A. M. Smihosky, M. Zeller, C. M. Zaleski, J. Chem. Crystallogr. 2021, 51, 465 – 482. | |
dc.identifier.citedreference | J. Wang, G. Lu, Y. Liu, S.-G. Wu, G.-Z. Huang, J.-L. Liu, M.-L. Tong, Cryst. Growth Des. 2019, 19, 1896 – 1902. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | I. D. Brown, D. Altermatt, Acta Crystallogr. 1985, B41, 244 – 247; | |
dc.identifier.citedreference | N. E. Brese, M. O′Keeffe, Acta Crystallogr. 1991, B47, 192 – 197; | |
dc.identifier.citedreference | W. Liu, H. H. Thorp, Inorg. Chem. 1993, 32, 4102 – 4105; | |
dc.identifier.citedreference | A. Trzesowska, R. Kruszynski, T. J. Bartezak, Acta Crystallogr. 2004, B60, 174 – 178. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | M. Llunell, D. Casanova, J. Cirera, P. Alemany, S. Alvarez, SHAPE, ver. 2.1, Barcelona (Spain), 2013; | |
dc.identifier.citedreference | M. Pinsky, D. Avnir, Inorg. Chem. 1998, 37, 5575 – 5582; | |
dc.identifier.citedreference | D. Casanova, J. Cirera, M. Llunell, P. Alemany, D. Avnir, S. Alvarez, J. Am. Chem. Soc. 2004, 126, 1755 – 1763; | |
dc.identifier.citedreference | J. Cirera, E. Ruiz, S. Alvarez, Organometallics 2005, 24, 1556 – 1562. | |
dc.identifier.citedreference | J. D. Rinehart, J. R. Long, Chem. Sci. 2011, 2, 2078 – 2085. | |
dc.identifier.citedreference | C. Loosli, S.-X. Liu, A. Neels, G. Labat, S. Decurtins, Z. Kristallogr. New Cryst. Struct. 2006, 221, 135 – 141. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Am. Chem. Soc. 2003, 125, 8694 – 8695; | |
dc.identifier.citedreference | N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Phys. Chem. B 2004, 108, 11265 – 11271; | |
dc.identifier.citedreference | N. Ishikawa, Y. Mizuno, S. Takamatsu, T. Ishikawa, S. Koshihara, Inorg. Chem. 2008, 47, 10217 – 10219. | |
dc.identifier.citedreference | H. C. Brown, D. H. McDaniel, O. Häfliger in Determination of Organic Structures by Physical Methods (Eds.: E. A. Braude, F. C. Nachod ), Academic Press Incs., 1955; pp. 567 – 662. | |
dc.identifier.citedreference | Bruker, Apex3 V2018.1-0, SAINT V8.38 A, Bruker AXS Inc., Madison (United States of America), 2018. | |
dc.identifier.citedreference | L. Krause, R. Herbst-Irmer, G. M. Sheldrick, D. Stalke, J. Appl. Crystallogr. 2015, 48, 3 – 10. | |
dc.identifier.citedreference | G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112 – 122. | |
dc.identifier.citedreference | G. M. Sheldrick, SHELXL2018, University of Göttingen, Göttingen (Germany), 2018. | |
dc.identifier.citedreference | G. M. Sheldrick, Acta Crystallogr. 2015, C71, 3 – 8. | |
dc.identifier.citedreference | C. B. Hübschle, G. M. Sheldrick, B. Dittrich, J. Appl. Crystallogr. 2011, 44, 1281 – 1284. | |
dc.identifier.citedreference | P. Van Der Sluis, A. L. Spek, Acta Crystallogr. 1990, A46, 194 – 201. | |
dc.identifier.citedreference | A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7 – 13. | |
dc.identifier.citedreference | A. L. Spek, Acta Crystallogr. 2009, D65, 148 – 155. | |
dc.identifier.citedreference | L. J. Farrugia, J. Appl. Crystallogr. 2012, 45, 849 – 854. | |
dc.identifier.citedreference | A. Lausi, M. Polentarutti, M. S. Onesti, J. R. Plaisier, E. Busetto, G. Bais, L. Barba, A. Cassetta, G. Campi, D. Lamba, A. Pifferi, S. C. Mande, D. D. Sarma, S. M. Sharma, G. Paolucci, Eur. Physiscs J. Plus 2015, 130, 43. | |
dc.identifier.citedreference | W. Kabsch, Acta Crystallogr. 2010, D66, 125 – 132. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | M. D. Winn, C. C. Ballard, K. D. Cowtan, E. J. Dodson, P. Emsley, P. R. Evans, R. M. Keegan, E. B. Krissinel, A. G. W. Leslie, A. McCoy, S. J. McNicholas, G. N. Murshudov, N. S. Pannu, E. A. Potterton, H. R. Powell, R. J. Read, A. Vagin, K. S. Wilson, Acta Crystallogr. 2011, D67, 235 – 242; | |
dc.identifier.citedreference | P. R. Evans, G. N. Murshudov, Acta Crystallogr. 2013, D69, 1204 – 1214. | |
dc.identifier.citedreference | O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 2009, 42, 339 – 341. | |
dc.identifier.citedreference | J. C. Lutter, B. A. Lopez Bermudez, T. N. Nguyen, J. W. Kampf, V. L. Pecoraro, J. Inorg. Biochem. 2019, 192, 119 – 125. | |
dc.identifier.citedreference | C. H. Hendon, A. J. Rieth, M. D. Korzyński, M. Dincă, ACS Cent. Sci. 2017, 3, 554 – 563. | |
dc.identifier.citedreference | C. Pu, H. Qin, Y. Gao, J. Zhou, P. Wang, X. Peng, J. Am. Chem. Soc. 2017, 139, 3302 – 3311. | |
dc.identifier.citedreference | M. P. U. Haris, R. Bakthavatsalam, S. Shaikh, B. P. Kore, D. Moghe, R. G. Gonnade, D. D. Sarma, D. Kabra, J. Kundu, Inorg. Chem. 2018, 57, 13443 – 13452. | |
dc.identifier.citedreference | J. Li, P. I. Djurovich, B. D. Alleyne, M. Yousufuddin, N. N. Ho, J. C. Thomas, J. C. Peters, R. Bau, M. E. Thompson, Inorg. Chem. 2005, 44, 1713 – 1727. | |
dc.identifier.citedreference | M. Ostrowska, I. O. Fritsky, E. Gumienna-Kontecka, A. V. Pavlishchuk, Coord. Chem. Rev. 2016, 327–328, 304 – 332. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | M. S. Lah, V. L. Pecoraro, Comments Inorg. Chem. 1990, 11, 59 – 84; | |
dc.identifier.citedreference | G. Mezei, C. M. Zaleski, V. L. Pecoraro, Chem. Rev. 2007, 107, 4933 – 5003. | |
dc.identifier.citedreference | J. J. Bodwin, A. D. Cutland, R. G. Malkani, V. L. Pecoraro, Coord. Chem. Rev. 2001, 216–217, 489 – 512. | |
dc.identifier.citedreference | C. Y. Chow, R. Guillot, E. Rivière, J. W. Kampf, T. Mallah, V. L. Pecoraro, Inorg. Chem. 2016, 55, 10238 – 10247. | |
dc.identifier.citedreference | T. T. Boron III, J. C. Lutter, C. I. Daly, C. Y. Chow, A. H. Davis, R. Nimthong, M. Zeller, J. W. Kampf, C. M. Zaleski, V. L. Pecoraro, Inorg. Chem. 2016, 55, 10597 – 10607. | |
dc.identifier.citedreference | C. M. Zaleski, J. W. Kampf, T. Mallah, M. L. Kirk, V. L. Pecoraro, Inorg. Chem. 2007, 45, 1954 – 1956. | |
dc.identifier.citedreference | C. M. Zaleski, S. Tricard, E. C. Depperman, W. Wernsdorfer, T. Mallah, M. L. Kirk, V. L. Pecoraro, Inorg. Chem. 2011, 50, 11348 – 11352. | |
dc.identifier.citedreference | C. M. Zaleski, E. C. Depperman, J. W. Kampf, M. L. Kirk, V. L. Pecoraro, Angew. Chem. Int. Ed. 2004, 43, 3912 – 3914; Angew. Chem. 2004, 116, 4002 – 4004. | |
dc.identifier.citedreference | C. Y. Chow, H. Bolvin, V. E. Campbell, R. Guillot, J. W. Kampf, W. Wernsdorfer, F. Gendron, J. Autschbach, V. L. Pecoraro, T. Mallah, Chem. Sci. 2015, 6, 4148 – 4159. | |
dc.identifier.citedreference | P. Happ, C. Plenk, E. Rentschler, Coord. Chem. Rev. 2015, 289–290, 238 – 260. | |
dc.identifier.citedreference | Y. Pavlyukh, E. Rentschler, H. J. Elmers, W. Hübner, G. Lefkidis, Phys. Rev. B 2018, 97, 1 – 19. | |
dc.identifier.citedreference | P. Happ, E. Rentschler, Dalton Trans. 2014, 43, 15308 – 15312. | |
dc.identifier.citedreference | S. V. Eliseeva, E. V. Salerno, B. A. Lopez Bermudez, S. Petoud, V. L. Pecoraro, J. Am. Chem. Soc. 2020, 142, 16173 – 16176. | |
dc.identifier.citedreference | E. R. Trivedi, S. V. Eliseeva, J. Jankolovits, M. M. Olmstead, V. L. Pecoraro, J. Am. Chem. Soc. 2014, 136, 1526 – 1534. | |
dc.identifier.citedreference | C. Y. Chow, S. V. Eliseeva, E. R. Trivedi, T. N. Nguyen, J. W. Kampf, S. Petoud, V. L. Pecoraro, J. Am. Chem. Soc. 2016, 138, 5100 – 5109. | |
dc.identifier.citedreference | T. N. Nguyen, S. V. Eliseeva, C. Y. Chow, J. W. Kampf, S. Petoud, V. L. Pecoraro, Inorg. Chem. Front. 2020, 7, 1553 – 1563. | |
dc.identifier.citedreference | ||
dc.identifier.citedreference | T. N. Nguyen, C. Y. Chow, S. V. Eliseeva, E. R. Trivedi, J. W. Kampf, I. Martinić, S. Petoud, V. L. Pecoraro, Chem. Eur. J. 2018, 24, 1031 – 1035; | |
dc.identifier.citedreference | E. V. Salerno, J. Zeler, S. V. Eliseeva, M. A. Hernández-Rodríguez, A. N. Carneiro Neto, S. Petoud, V. L. Pecoraro, L. D. Carlos, Chem. Eur. J. 2020, 26, 13792 – 13796. | |
dc.identifier.citedreference | J. C. Lutter, S. V. Eliseeva, G. Collet, I. Martinic, J. W. Kampf, B. L. Schneider, A. Carichner, J. Sobilo, S. Lerondel, S. Petoud, V. L. Pecoraro, Chem. Eur. J. 2019, 26, 1274 – 1277. | |
dc.identifier.citedreference | J. Jankolovits, C. M. Andolina, J. W. Kampf, K. N. Raymond, V. L. Pecoraro, Angew. Chem. Int. Ed. 2011, 50, 9660 – 9664; Angew. Chem. 2011, 123, 9834 – 9838. | |
dc.identifier.citedreference | J. Ferrando-Soria, J. Vallejo, M. Castellano, J. Martínez-Lillo, E. Pardo, J. Cano, I. Castro, F. Lloret, R. Ruiz-García, M. Julve, Coord. Chem. Rev. 2017, 339, 17 – 103. | |
dc.identifier.citedreference | G. Aromí, F. Luis, O. Roubea, in Lanthanides and Actinides in Molecular Magnetism, (Eds.: R. A. Layfield, M. Murugesu ), Wiley-VCH Verlap & Co. KGaA, Weinheim, Germany, 2015; pp. 185 – 221. | |
dc.identifier.citedreference | M. R. Azar, T. T. Boron III, J. C. Lutter, C. I. Daly, K. A. Zegalia, R. Nimthong, G. M. Ferrence, M. Zeller, J. W. Kampf, V. L. Pecoraro, C. M. Zaleski, Inorg. Chem. 2014, 53, 1729 – 1742. | |
dc.identifier.citedreference | F. Cao, R.-M. Wei, J. Li, L. Yang, Y. Han, Y. Song, J. Dou, Inorg. Chem. 2016, 55, 5914 – 5923. | |
dc.identifier.citedreference | J. R. Travis, A. M. Smihosky, A. C. Kauffman, S. E. Ramstrom, A. J. Lewis, S. G. Nagy, R. E. Rheam, M. Zeller, C. M. Zaleski, J. Chem. Crystallogr. 2021, 51, 372 – 393. | |
dc.working.doi | NO | en |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.