Voltage-Modulated Untwist Deformations and Multispectral Optical Effects from Ion Intercalation into Chiral Ceramic Nanoparticles
dc.contributor.author | Shao, Xiao | |
dc.contributor.author | Zhu, Cheng | |
dc.contributor.author | Kumar, Prashant | |
dc.contributor.author | Wang, Yanan | |
dc.contributor.author | Lu, Jun | |
dc.contributor.author | Cha, Minjeong | |
dc.contributor.author | Yao, Lin | |
dc.contributor.author | Cao, Yuan | |
dc.contributor.author | Mao, Xiaoming | |
dc.contributor.author | Heinz, Hendrik | |
dc.contributor.author | Kotov, Nicholas A. | |
dc.date.accessioned | 2023-05-01T19:12:33Z | |
dc.date.available | 2024-05-01 15:12:28 | en |
dc.date.available | 2023-05-01T19:12:33Z | |
dc.date.issued | 2023-04 | |
dc.identifier.citation | Shao, Xiao; Zhu, Cheng; Kumar, Prashant; Wang, Yanan; Lu, Jun; Cha, Minjeong; Yao, Lin; Cao, Yuan; Mao, Xiaoming; Heinz, Hendrik; Kotov, Nicholas A. (2023). "Voltage-Modulated Untwist Deformations and Multispectral Optical Effects from Ion Intercalation into Chiral Ceramic Nanoparticles." Advanced Materials 35(16): n/a-n/a. | |
dc.identifier.issn | 0935-9648 | |
dc.identifier.issn | 1521-4095 | |
dc.identifier.uri | https://hdl.handle.net/2027.42/176314 | |
dc.description.abstract | Reconfiguration of chiral ceramic nanostructures after ion intercalation should favor specific nanoscale twists leading to strong chiroptical effects. In this work, V2O3 nanoparticles are shown to have “built-in” chiral distortions caused by binding of tartaric acid enantiomers to the nanoparticle surface. As evidenced by spectroscopy/microscopy techniques and calculations of nanoscale chirality measures, the intercalation of Zn2+ ions into the V2O3 lattice results in particle expansion, untwist deformations, and chirality reduction. Coherent deformations in the particle ensemble manifest as changes in sign and positions of circular polarization bands at ultraviolet, visible, mid-infrared (IR), near-IR (NIR), and IR wavelengths. The g-factors observed for IR and NIR spectral diapasons are ≈100–400 times higher than those for previously reported dielectric, semiconductor, and plasmonic nanoparticles. Nanocomposite films layer-by-layer assembled (LBL) from V2O3 nanoparticles reveal cyclic-voltage-driven modulation of optical activity. Device prototypes for IR and NIR range problematic for liquid crystals and other organic materials are demonstrated. High optical activity, synthetic simplicity, sustainable processability, and environmental robustness of the chiral LBL nanocomposites provide a versatile platform for photonic devices. Similar reconfigurations of particle shapes are expected for multiple chiral ceramic nanostructures, leading to unique optical, electrical, and magnetic properties.Chiral V2O3 nanoparticles display rich palette of intense chiroptical bands. Intercalation–deintercalation of Zn2+ leads to twist–untwist deformation and modulation of optical activity, which is remarkably strong for IR and NIR range because V2O3 nanoparticles have g-factors ≈100–400 times higher than other nanostructures. Device prototypes based on layer-by-layer assembled nanocomposite films provide a pathway to versatile voltage-driven photonic devices. | |
dc.publisher | Wiley Periodicals, Inc. | |
dc.subject.other | chiral photonics | |
dc.subject.other | metamaterials | |
dc.subject.other | nanoscale chirality | |
dc.subject.other | polarization rotation | |
dc.subject.other | twist deformations | |
dc.title | Voltage-Modulated Untwist Deformations and Multispectral Optical Effects from Ion Intercalation into Chiral Ceramic Nanoparticles | |
dc.type | Article | |
dc.rights.robots | IndexNoFollow | |
dc.subject.hlbsecondlevel | Materials Science and Engineering | |
dc.subject.hlbsecondlevel | Engineering (General) | |
dc.subject.hlbtoplevel | Engineering | |
dc.description.peerreviewed | Peer Reviewed | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/176314/1/adma202206956.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/176314/2/adma202206956-sup-0001-SuppMat.pdf | |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/176314/3/adma202206956_am.pdf | |
dc.identifier.doi | 10.1002/adma.202206956 | |
dc.identifier.source | Advanced Materials | |
dc.identifier.citedreference | C. Hao, R. Gao, Y. Li, L. Xu, M. Sun, C. Xu, H. Kuang, Angew. Chem., Int. Ed. 2019, 58, 7371. | |
dc.identifier.citedreference | Z. Wang, L. Jing, K. Yao, Y. Yang, B. Zheng, C. M. Soukoulis, H. Chen, Y. Liu, Adv. Mater. 2017, 29, 1700412. | |
dc.identifier.citedreference | W. J. Choi, G. Cheng, Z. Huang, S. Zhang, T. B. Norris, N A. Kotov, Nat. Mater. 2019, 18, 820. | |
dc.identifier.citedreference | A. Kuzyk, Y. Yang, X. Duan, S. Stoll, A. O. Govorov, H. Sugiyama, M. Endo, N. Liu, Nat. Commun. 2016, 7, 10591. | |
dc.identifier.citedreference | I. Fernandez-Corbaton, C. Rockstuhl, P. Ziemke, P. Gumbsch, A. Albiez, R. Schwaiger, T. Frenzel, M. Kadic, M. Wegener, Adv. Mater. 2019, 31, 1807742. | |
dc.identifier.citedreference | S. Wang, Y. Zhang, X. Qin, Li Zhang, Z. Zhang, W. Lu, M. Liu, ACS Nano 2020, 14, 6087. | |
dc.identifier.citedreference | J. K. Gansel, M. Thiel, M. S. Rill, M. Decker, K. Bade, V. Saile, G. Von Freymann, S. Linden, M. Wegener, Science 2009, 325, 1513. | |
dc.identifier.citedreference | Z. Suo, X. Hou, J. Chen, X. Liu, Y. Liu, F. Xing, Y. Chen, L. Feng, J. Phys. Chem. C 2020, 124, 21094. | |
dc.identifier.citedreference | S. Zhang, J. Zhou, Y. -. S. Park, J. Rho, R. Singh, S. Nam, A. K. Azad, H. -. T. Chen, X. Yin, A. J. Taylor, X. Zhang, Nat. Commun. 2012, 3, 942. | |
dc.identifier.citedreference | G. Wu, K. Du, C. Xia, X. Kun, J. Shen, B. Zhou, J. Wang, Thin Solid Films 2005, 485, 284. | |
dc.identifier.citedreference | W. Zhang, H. Li, M. Al-Hussein, A. Y. Elezzabi, Adv. Opt. Mater. 2020, 8, 1901224. | |
dc.identifier.citedreference | I. Mjejri, A. Rougier, M. Gaudon, Inorg. Chem. 2017, 56, 1734. | |
dc.identifier.citedreference | J. Zheng, Y. Zhang, C. Meng, X. Wang, C. Liu, M. Bo, X. Pei, Y. Wei, T. Lv, G. Cao, Electrochim. Acta 2019, 318, 635. | |
dc.identifier.citedreference | C. Marini, E. Arcangeletti, D. Di Castro, L. Baldassare, A. Perucchi, S. Lupi, L. Malavasi, L. Boeri, E. Pomjakushina, K. Conder, P. Postorino, Phys. Rev. B 2008, 77, 235111. | |
dc.identifier.citedreference | H. Heinz, T. -. J. Lin, R. Kishore Mishra, F. S. Emami, Langmuir 2013, 29, 1754. | |
dc.identifier.citedreference | S. H. Jung, J. Jeon, H. Kim, J. Jaworski, J. H. Jung, J. Am. Chem. Soc. 2014, 136, 6446. | |
dc.identifier.citedreference | I. Dolamic, B. Varnholt, T. Bürgi, Nat. Commun. 2015, 6, 7117. | |
dc.identifier.citedreference | M. A. Osipov, B. T. Pickup, D. A. Dunmur, Mol. Phys. 1995, 84, 1193. | |
dc.identifier.citedreference | A. B. Harris, R. D. Kamien, T. C. Lubensky, Rev. Mod. Phys. 1999, 71, 1745. | |
dc.identifier.citedreference | P. Kumar, T. Vo, M. Cha, A. Visheratin, J.-Y. Kim, W. Xu, J. Schwartz, A. Simon, D. Katz, E. Marino, W. J. Choi, S. Chen, C. Murray, R. Hovden, S. Glotzer, N. A. Kotov, Nature 2022 https://doi.org/10.1038/s41586-023-05733-1. | |
dc.identifier.citedreference | S. Jiang, M. Chekini, Z. -. B. Qu, Y. Wang, A. Yeltik, Y. Liu, A. Kotlyar, T. Zhang, B. Li, H. V. Demir, N. A. Kotov, J. Am. Chem. Soc. 2017, 139, 13701. | |
dc.identifier.citedreference | J. L. Shelton, K. E. Knowles, J. Phys. Chem. Lett. 2021, 12, 3343. | |
dc.identifier.citedreference | P.-P. Wang, S.-J. Yu, A. O. Govorov, M. Ouyang, Nat. Commun. 2017, 8, 14312. | |
dc.identifier.citedreference | J. Yan, W. Feng, J.-Y. Kim, J. Lu, P. Kumar, Z. Mu, X. Wu, X. Mao, N. A. Kotov, Chem. Mater. 2020, 32, 476. | |
dc.identifier.citedreference | L. Ma, Y. Cao, Y. Duan, L. Han, S. Che, Angew. Chem., Int. Ed. 2017, 56, 8657. | |
dc.identifier.citedreference | N. Zhang, M. Jia, Y. Dong, Y. Wang, J. Xu, Y. Liu, L. Jiao, F. Cheng, Adv. Funct. Mater. 2019, 29, 1807331. | |
dc.identifier.citedreference | Y. Kim, B. Yeom, O. Arteaga, S. Jo Yoo, S. -. G. Lee, J. -. G. Kim, N. A. Kotov, Nat. Mater. 2016, 15, 461. | |
dc.identifier.citedreference | P. T. Probst, M. Mayer, V. Gupta, A. M. Steiner, Z. Zhou, G. K. Auernhammer, T. A. F. König, A. Fery, Nat. Mater. 2021, 20, 1024. | |
dc.identifier.citedreference | Z. Li, Z. Zhu, W. Liu, Y. Zhou, B. Han, Y. Gao, Z. Tang, J. Am. Chem. Soc. 2012, 134, 3322. | |
dc.identifier.citedreference | Y. Wang, Y.-M. Zhang, S. X-A. Zhang, Acc. Chem. Res. 2021, 54, 2216. | |
dc.identifier.citedreference | K. Ariga, J. P. Hill, Q. Ji, Phys. Chem. Chem. Phys. 2007, 9, 2319. | |
dc.identifier.citedreference | S. Zhao, F. Caruso, L. Dahne, G. Decher, B. G. de Geest, J. Fan, N. Feliu, Y. Gogotsi, P. T. Hammond, M. C. Hersam, A. Khademhosseini, N. Kotov, S. Leporatti, Y. Li, F. Lisdat, L. M. Liz-Marzan, S. Moya, P. Mulvaney, A. L. Rogach, S. Roy, D. G. Shchukin, A. G. Skirtach, M. M. Stevens, G. B. Sukhorukov, P. S. Weiss, Z. Yue, D. Zhu, W. J. Parak, ACS Nano 2019, 13, 6151. | |
dc.identifier.citedreference | G. Yang, Q. Li, K. Ma, C. Hong, C. Wang, J. Mater. Chem. A 2020, 8, 8084. | |
dc.identifier.citedreference | R. Hausbrand, G. Cherkashinin, H. Ehrenberg, M. Gröting, K. Albe, C. Hess, W. Jaegermann, Mater. Sci. Eng., B 2015, 192, 3. | |
dc.identifier.citedreference | J. Yeom, U. S. Santos, M. Chekini, M. Cha, A. F. De Moura, N. A. Kotov, Science 2018, 359, 309. | |
dc.identifier.citedreference | S. Knoppe, T. Bürgi, Acc. Chem. Res. 2014, 47, 1318. | |
dc.working.doi | NO | en |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.