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Reversible Thermochromic Bismuth Iodide Enabled by Self-Adjustment
dc.contributor.authorWen, Rui
dc.contributor.authorWang, Yanyan
dc.contributor.authorMa, Xinjie
dc.contributor.authorYan, Yikun
dc.contributor.authorMa, Qi
dc.contributor.authorGao, Jinpeng
dc.contributor.authorSun, Huaming
dc.contributor.authorHuang, Hao
dc.contributor.authorGao, Ziwei
dc.date.accessioned2023-06-01T20:52:54Z
dc.date.available2024-06-01 16:52:51en
dc.date.available2023-06-01T20:52:54Z
dc.date.issued2023-05
dc.identifier.citationWen, Rui; Wang, Yanyan; Ma, Xinjie; Yan, Yikun; Ma, Qi; Gao, Jinpeng; Sun, Huaming; Huang, Hao; Gao, Ziwei (2023). "Reversible Thermochromic Bismuth Iodide Enabled by Self-Adjustment." Advanced Optical Materials 11(9): n/a-n/a.
dc.identifier.issn2195-1071
dc.identifier.issn2195-1071
dc.identifier.urihttps://hdl.handle.net/2027.42/176902
dc.description.abstractLight-harvesting materials with dynamical management of light transmittance hold great promise in smart photovoltaics (PV). Here, a novel organic–inorganic halide, MVBi2I8 (MV = methyl viologen cation), exhibiting reversible thermochromism and constant bandgap of ≈1.65 eV over a wide temperature range of 77–453 K, is presented as a candidate. The compound consists of 0D (Bi4I16)4– clusters and MV2+ cations. And the adjacent (Bi4I16)4– clusters are in touch with each other, forming a 3D interaction for the inorganic part. The experimental and theoretical studies reveal that the ionic and covalent interactions in the crystal undergo a self-adjusting process in response to temperature changes. The self-adjustment and electron transfer between inorganic clusters and organic cations enable excellent reversible thermochromism and constant narrow bandgaps over a wide temperature range, which is expected for smart PV windows integrated with information displays and potentially other technologies.A novel organic–inorganic halide, MVBi2I8, is presented as a light-harvesting candidate for smart photovoltaic windows for its reversible thermochromism and constant bandgap of ≈1.65 eV from 77 to 453 K. The self-adjustment and electron transfer between inorganic clusters and organic cations were demonstrated to give it such unique properties.
dc.publisherWiley Periodicals, Inc.
dc.subject.othersmart photovoltaics
dc.subject.otherthermochromism
dc.subject.otherbandgaps
dc.subject.otherhybrid halides
dc.subject.otherself-adjustment
dc.titleReversible Thermochromic Bismuth Iodide Enabled by Self-Adjustment
dc.typeArticle
dc.rights.robotsIndexNoFollow
dc.subject.hlbsecondlevelMaterials Science and Engineering
dc.subject.hlbtoplevelEngineering
dc.description.peerreviewedPeer Reviewed
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/176902/1/adom202203148.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/176902/2/adom202203148-sup-0001-SuppMat.pdf
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/176902/3/adom202203148_am.pdf
dc.identifier.doi10.1002/adom.202203148
dc.identifier.sourceAdvanced Optical Materials
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dc.owningcollnameInterdisciplinary and Peer-Reviewed


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