121Sb nuclear gamma-ray resonance study of crystal chemical structures in U---Sb---O acrylonitrile catalysts
dc.contributor.author | Evans, B. J. | en_US |
dc.date.accessioned | 2006-04-07T16:30:39Z | |
dc.date.available | 2006-04-07T16:30:39Z | |
dc.date.issued | 1976-02 | en_US |
dc.identifier.citation | Evans, B. J. (1976/02)."121Sb nuclear gamma-ray resonance study of crystal chemical structures in U---Sb---O acrylonitrile catalysts." Journal of Catalysis 41(2): 271-276. <http://hdl.handle.net/2027.42/21832> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHJ-4CFY82M-RC/2/bbd24b0889951a7256d31bdd006b210f | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/21832 | |
dc.description.abstract | 121Sb Nuclear-gamma-ray resonance measurements have been made at 77 [deg]K on USb2O10, USbO5 and on a commerical supported catalyst preparation 60 wt% USb4.6Ox-40 wt% SiO2. The NGR spectrum of USbO5 is consistent with a single Sb site. The spectrum of USb3O10 is interpreted as resulting from more than one Sb site. In both materials, the covalency of the Sb sites is greater than that in pure Sb---O phases such as Sb2O4 and Sb2O5. The NGR data are consistent with both USbO5 and USb3O10 being catalytically active and with previous conclusions based on kinetic data that differences in the selectivity of USbO5 and USb3O10 result from differences in atomic topologies and geometries. | en_US |
dc.format.extent | 493136 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | 121Sb nuclear gamma-ray resonance study of crystal chemical structures in U---Sb---O acrylonitrile catalysts | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Crystal Chemistry and Crystal Physics Laboratories, Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48104, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/21832/1/0000235.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9517(76)90342-0 | en_US |
dc.identifier.source | Journal of Catalysis | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.