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Microwave spectrum and structure of ethylene ozonide: Effects of large axes rotations in structure calculations
dc.contributor.authorKuczkowski, Robert L.en_US
dc.contributor.authorGillies, C. W.en_US
dc.contributor.authorGallaher, K. L.en_US
dc.date.accessioned2006-04-07T16:32:49Z
dc.date.available2006-04-07T16:32:49Z
dc.date.issued1976-03-30en_US
dc.identifier.citationKuczkowski, Robert L., Gillies, C. W., Gallaher, K. L. (1976/03/30)."Microwave spectrum and structure of ethylene ozonide: Effects of large axes rotations in structure calculations." Journal of Molecular Spectroscopy 60(1-3): 361-372. <http://hdl.handle.net/2027.42/21905>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WK8-4CRG9P2-9W/2/53ef6a26329a37ff9b5764a9d38d1052en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/21905
dc.description.abstractRotational spectra for 14 isotopic species of ethylene ozonide have now been assigned. The consistency of the Kraitchman substitution structure was checked by calculating the Op---Op bond distance six ways; the values ranged from 1.458 to 1.502 A. This variation was attributed to an amplification of residual vibrational effects by large axes rotations upon isotopic substitution. Estimates of errors produced from this effect were made and a procedure was developed for choosing rs parameters in which the effect is minimized. This gave the following ring parameters: d(COe) = 1.416 A, d(COp) = 1.412 A, d(OO) = 1.461 A, eC = 104.8[deg], eCOp = 105.5[deg], pOp = 99.3[deg].en_US
dc.format.extent804703 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleMicrowave spectrum and structure of ethylene ozonide: Effects of large axes rotations in structure calculationsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelPhysicsen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/21905/1/0000312.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-2852(76)90139-9en_US
dc.identifier.sourceJournal of Molecular Spectroscopyen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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