Microwave spectrum and structure of ethylene ozonide: Effects of large axes rotations in structure calculations
dc.contributor.author | Kuczkowski, Robert L. | en_US |
dc.contributor.author | Gillies, C. W. | en_US |
dc.contributor.author | Gallaher, K. L. | en_US |
dc.date.accessioned | 2006-04-07T16:32:49Z | |
dc.date.available | 2006-04-07T16:32:49Z | |
dc.date.issued | 1976-03-30 | en_US |
dc.identifier.citation | Kuczkowski, Robert L., Gillies, C. W., Gallaher, K. L. (1976/03/30)."Microwave spectrum and structure of ethylene ozonide: Effects of large axes rotations in structure calculations." Journal of Molecular Spectroscopy 60(1-3): 361-372. <http://hdl.handle.net/2027.42/21905> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WK8-4CRG9P2-9W/2/53ef6a26329a37ff9b5764a9d38d1052 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/21905 | |
dc.description.abstract | Rotational spectra for 14 isotopic species of ethylene ozonide have now been assigned. The consistency of the Kraitchman substitution structure was checked by calculating the Op---Op bond distance six ways; the values ranged from 1.458 to 1.502 A. This variation was attributed to an amplification of residual vibrational effects by large axes rotations upon isotopic substitution. Estimates of errors produced from this effect were made and a procedure was developed for choosing rs parameters in which the effect is minimized. This gave the following ring parameters: d(COe) = 1.416 A, d(COp) = 1.412 A, d(OO) = 1.461 A, eC = 104.8[deg], eCOp = 105.5[deg], pOp = 99.3[deg]. | en_US |
dc.format.extent | 804703 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Microwave spectrum and structure of ethylene ozonide: Effects of large axes rotations in structure calculations | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/21905/1/0000312.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0022-2852(76)90139-9 | en_US |
dc.identifier.source | Journal of Molecular Spectroscopy | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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