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Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4
dc.contributor.authorBartel, James J.en_US
dc.contributor.authorWestrum, Jr. , Edgar F.en_US
dc.contributor.authorHaas, Jr. , John L.en_US
dc.date.accessioned2006-04-07T16:33:09Z
dc.date.available2006-04-07T16:33:09Z
dc.date.issued1976-06en_US
dc.identifier.citationBartel, James J., Westrum, Jr., Edgar F., Haas, Jr., John L. (1976/06)."Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4." The Journal of Chemical Thermodynamics 8(6): 575-581. <http://hdl.handle.net/2027.42/21916>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHM-4CRH94D-DT/2/e1170b8593807c318f181cbd3d095f20en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/21916
dc.description.abstractThe heat capacity of a hydrothermally-prepared polycrystalline sample of Fe3O4 was measured from 53 to 350 K, primarily to study the thermophysics of the Verwey transitions. Although the bifurcation of the transition was confirmed, the sample was found to contain traces of manganese. The observed transition temperatures of 117.0 and 123.0 K are 3.7 and 4.2 K higher respectively than those found in pure Fe3O4. Ancillary analytical results are consistent and indicate a stoichiometry of Mn0.008Fe2.992O4 for this material. Characteristics in the transition region are ascribed to dopant effects.en_US
dc.format.extent404863 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A.; U.S. Geological Survey, National Center, Stop 959, Reston, Virginia 22092, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A.; U.S. Geological Survey, National Center, Stop 959, Reston, Virginia 22092, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A.; U.S. Geological Survey, National Center, Stop 959, Reston, Virginia 22092, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/21916/1/0000323.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0021-9614(76)90031-8en_US
dc.identifier.sourceThe Journal of Chemical Thermodynamicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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