Low-temperature heat capacities of three molybdenum oxychlorides
dc.contributor.author | Kiwia, Harmas L. | en_US |
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.date.accessioned | 2006-04-07T16:41:56Z | |
dc.date.available | 2006-04-07T16:41:56Z | |
dc.date.issued | 1975-10 | en_US |
dc.identifier.citation | Kiwia, Harmas L., Westrum, Jr, Edgar F. (1975/10)."Low-temperature heat capacities of three molybdenum oxychlorides." The Journal of Chemical Thermodynamics 7(10): 983-992. <http://hdl.handle.net/2027.42/22198> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4CRHCWG-14Y/2/1011c9b146a6cd28e1be46b1b22c3461 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/22198 | |
dc.description.abstract | The heat capacities of MoO2Cl2, McOCl3, and MoOCl4 have been determined from 5 to 350 K. No thermal anomalies were detected over this temperature range. At 298.15 K the values of the heat capacity Cp, entropy So, and the function {Go(T) - Ho(0)/T} found were (for MoO2Cl2), 24.53, 32.42, and -16.71 kcalth K-1 mol-1; (for MoOCl3), 26.85 39.16, and -20.94 kcalth K-1 mol-1; and (for MoOCl4), 33.44, 48.28, and -25.80 kcalth K-1 mol-1. The derived functions stated above assume the extrapolation of the observed results from 0 to 5 K to follow the Debye limiting law; i.e., possible magnetic thermal anomalies below 5 K have not been included. | en_US |
dc.format.extent | 550386 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Low-temperature heat capacities of three molybdenum oxychlorides | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48104, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/22198/1/0000629.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9614(75)90163-9 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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