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An energy denominator study of the phonon side band in isotopic mixed naphthalene crystals
dc.contributor.authorOchs, Frederick W.en_US
dc.contributor.authorPrasad, Paras N.en_US
dc.contributor.authorKopelman, Raoulen_US
dc.date.accessioned2006-04-07T16:42:56Z
dc.date.available2006-04-07T16:42:56Z
dc.date.issued1974-11-15en_US
dc.identifier.citationOchs, Frederick W., Prasad, Paras N., Kopelman, Raoul (1974/11/15)."An energy denominator study of the phonon side band in isotopic mixed naphthalene crystals." Chemical Physics Letters 29(2): 290-294. <http://hdl.handle.net/2027.42/22232>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TFN-44W4TKJ-6N/2/38cbaa0f714c4ad2ac0ec3684fd194acen_US
dc.identifier.urihttps://hdl.handle.net/2027.42/22232
dc.description.abstractThe fluorescence phonon sidebands of C10H8 and 1,4,5,8-C10D4H4 guests in C10H8 are studied and compared at 2 K. The mild differences are attributed to the increased delocalization of the C10D4H4 1B2u electronic state. The relative importance of the diagonal (Franck-Condon) versus off-diagonal (Herzberg-Teller) electron-phonon coupling terms is discussed. We also demonstrate that the dispersion force coupling (and not the resonance force coupling) dominates the 1B2u (and 3B1u) C10H8 in C10D8 phonon sideband structure, and is responsible for its intensity distribution (and the difference therein between fluorescence and phosphorescence).en_US
dc.format.extent592464 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleAn energy denominator study of the phonon side band in isotopic mixed naphthalene crystalsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48104, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48104, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48104, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/22232/1/0000666.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0009-2614(74)85034-7en_US
dc.identifier.sourceChemical Physics Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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