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Spectroscopic evidence for a continuous change in molecular and crystal structure: deformation of biphenyl in the low temperature solid
dc.contributor.authorFriedman, Peter S.en_US
dc.contributor.authorKopelman, Raoulen_US
dc.contributor.authorPrasad, Paras N.en_US
dc.date.accessioned2006-04-07T16:49:10Z
dc.date.available2006-04-07T16:49:10Z
dc.date.issued1974-01-01en_US
dc.identifier.citationFriedman, Peter S., Kopelman, Raoul, Prasad, Paras N. (1974/01/01)."Spectroscopic evidence for a continuous change in molecular and crystal structure: deformation of biphenyl in the low temperature solid." Chemical Physics Letters 24(1): 15-17. <http://hdl.handle.net/2027.42/22435>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TFN-44GG54S-83/2/3720151ef7b5514d7059c53c4cbc48b1en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/22435
dc.description.abstractA Raman temperature study of biphenyl-h10 and biphenyl-d10 crystals reveals an unusual spectral change over a wide temperature region. Many internal and external infrared-active modes appear gradually as the temperature is lowered from about 75 to 15[deg]K. We interpret this as a mild and gradual change in both crystal and molecular structure: a loss of center of inversion, probably involving the partial return of the molecule to its non-planar shape (D2) in the vapor phase.en_US
dc.format.extent249142 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleSpectroscopic evidence for a continuous change in molecular and crystal structure: deformation of biphenyl in the low temperature soliden_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michican 48104, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michican 48104, USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michican 48104, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/22435/1/0000886.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0009-2614(74)80201-0en_US
dc.identifier.sourceChemical Physics Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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