Electrochemical reduction of 2-hydroxypyrimidine in dimethylsulfoxide : Influence of the father-son reaction
dc.contributor.author | Wasa, Tamotsu | en_US |
dc.contributor.author | Elving, Philip Juliber | en_US |
dc.date.accessioned | 2006-04-07T16:59:46Z | |
dc.date.available | 2006-04-07T16:59:46Z | |
dc.date.issued | 1978-08-10 | en_US |
dc.identifier.citation | Wasa, Tamotsu, Elving, Philip J. (1978/08/10)."Electrochemical reduction of 2-hydroxypyrimidine in dimethylsulfoxide : Influence of the father-son reaction." Journal of Electroanalytical Chemistry 91(2): 249-264. <http://hdl.handle.net/2027.42/22551> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGB-44YR2V2-23/2/28b31f5d4e32379c637824cfae663e26 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/22551 | |
dc.description.abstract | In DMSO (0.1 M TEAP), 2-hydroxypyrimidine (2-HP) is reversibly reduced (1e process) to a radical anion, whose dimerization is slower than its attack (it is a strong base) on unreduced 2-HP to abstract a proton (father-son reaction), producing the neutral free radical, which dimerizes more rapidly than the radical anion, and the anion of 2-HP, which can be involved in a Hg(I)---Hg(O) couple; the apparent faradaic n is less than one. On addition of strong base to a 2-HP solution, the 2-HP is converted to the anion and the only electrochemical activity seen is that due to the mercury couple. On strong acid addition, the protonated 2-HP formed is more easily reduced than neutral 2-HP; the resulting current considerably exceeds that for 2-HP itself (faradaic n equals one); the anion-mercury reaction couple is not seen. The neutral free radical formed rapidly dimerizes. Weak acid addition produces an adduct due to hydrogen bridging between acid anion and pyrimidine reduction site; reduction to the neutral free radical is facilitated; the weak acid anion is involved in a Hg(I)---Hg(O) couple at a potential characteristic for the acid used; the mercury-pyridimine anion couple occurs at a potential characteristic for 2-HP. | en_US |
dc.format.extent | 1343887 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Electrochemical reduction of 2-hydroxypyrimidine in dimethylsulfoxide : Influence of the father-son reaction | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | The University of Michigan, Ann Arbor, Mich., 48109 U.S.A.; Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture, Sakai, Japan. | en_US |
dc.contributor.affiliationum | The University of Michigan, Ann Arbor, Mich., 48109 U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/22551/1/0000096.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0368-1874(78)85095-3 | en_US |
dc.identifier.source | Journal of Electroanalytical Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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