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Electrophilic alkylation of 1-SB9H9
dc.contributor.authorMeneghelli, B. J.en_US
dc.contributor.authorRudolph, Ralph Williamen_US
dc.date.accessioned2006-04-07T17:10:29Z
dc.date.available2006-04-07T17:10:29Z
dc.date.issued1977-06-21en_US
dc.identifier.citationMeneghelli, B. J., Rudolph, R. W. (1977/06/21)."Electrophilic alkylation of 1-SB9H9." Journal of Organometallic Chemistry 133(2): 139-145. <http://hdl.handle.net/2027.42/22894>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-42YDFY8-VW/2/e71d72f55068449c95c6a4d8144028e0en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/22894
dc.description.abstractReaction of closo-1-SB9H9 with either ethyl or methyl iodide in the presence of A1C13 produces alkylated derivatives of the type 1-SB9H(9-x)Rx (R = C2H5, CH3;x = 1---5), which were identified by GC/MS, 11B and 1H NMR spectroscopy. The initial product is 6-R-1-SB9H8 rather than the 10-R-1-SB9H8 predicted on the basis of ground-state charge considerations. Thus, these results are as found for halogenation of 1-SB9H9 but differ from the precedent set by substitution reactions in closo-carboranes.en_US
dc.format.extent526981 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleElectrophilic alkylation of 1-SB9H9en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumChemistry Department, University of Michigan, Ann Arbor, Michigan 48109 U.S.A.en_US
dc.contributor.affiliationumChemistry Department, University of Michigan, Ann Arbor, Michigan 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/22894/1/0000458.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0022-328X(00)92867-5en_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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