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Microwave spectrum, structure, quadrupole coupling constants and dipole moment of carbon monoxide-borane
dc.contributor.authorVenkatachar, A. C.en_US
dc.contributor.authorTaylor, R. C.en_US
dc.contributor.authorKuczkowski, Robert L.en_US
dc.date.accessioned2006-04-07T17:11:25Z
dc.date.available2006-04-07T17:11:25Z
dc.date.issued1977-05en_US
dc.identifier.citationVenkatachar, A. C., Taylor, R. C., Kuczkowski, R. L. (1977/05)."Microwave spectrum, structure, quadrupole coupling constants and dipole moment of carbon monoxide-borane." Journal of Molecular Structure 38(): 17-23. <http://hdl.handle.net/2027.42/22924>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGS-44BMTJG-4V/2/11aff422a75af0b1bdcebc4e22e16e86en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/22924
dc.description.abstractThe J = 0 --&gt; 1 and J = 1 --&gt; 2 transitions of thirteen isotopic species of carbon monoxide-borane (BH3CO) have been measured. The heavy atom r2 structural parameters have been calculated in several ways so as to minimize the effects of the small carbon coordinate. The structural parameters found are: d(B-C) = 1.534 +/- 0.01 A, d(C-O)= 1.135 +/- 0.01 A. d(B-H)= 1.221 +/- 0.001 A, [angle]HBC = 103.79 +/- 0.06[deg], and [angle]HBH = 114.50 +/- 0.15[deg]. In addition, a complete r0 structure has been calculated by least-squares fitting the moments of inertia of all the isotopic species. A dipole moment of 1.698 +/- 0.02 D was determined.en_US
dc.format.extent583338 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleMicrowave spectrum, structure, quadrupole coupling constants and dipole moment of carbon monoxide-boraneen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry. The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.; Division of Mathematics and Science, Cleveland State Community College, Cleveland, Tenn. 37311.en_US
dc.contributor.affiliationumDepartment of Chemistry. The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry. The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/22924/1/0000489.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-2860(77)87074-9en_US
dc.identifier.sourceJournal of Molecular Structureen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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