The stereochemistry of ethylene-1,2-d2 epoxidation over silver catalysts
dc.contributor.author | Egashira, Makoto | en_US |
dc.contributor.author | Kuczkowski, Robert L. | en_US |
dc.contributor.author | Cant, Noel W. | en_US |
dc.date.accessioned | 2006-04-07T17:21:19Z | |
dc.date.available | 2006-04-07T17:21:19Z | |
dc.date.issued | 1980-10 | en_US |
dc.identifier.citation | Egashira, Makoto, Kuczkowski, Robert L., Cant, Noel W. (1980/10)."The stereochemistry of ethylene-1,2-d2 epoxidation over silver catalysts." Journal of Catalysis 65(2): 297-310. <http://hdl.handle.net/2027.42/23136> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHJ-4CFW57J-J3/2/560822a0216e045aad0dbacfaac57f91 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/23136 | |
dc.description.abstract | The stereochemistry of the catalytic epoxidation of cis-ethylene-1,2-d2 to ethylene oxide over four unsupported and two supported silver catalysts as well as over Ag2O and AgO was studied. Variations of the stereochemistry with reaction composition including addition of C4H2Cl2 to moderate the catalyst and the use of N2O as the oxidant were also explored. Equilibration in the product ranged between 57 and 99%. A correlation in the equilibration with extent of oxidation of the surface was proposed. Several models were discussed which could rationalize the observed partial equilibration and the sensitivity of the randomization kinetics to certain reaction variables such as oxygen concentration or addition of C2H4Cl2 or N2O but not others such as temperature and catalyst selectivity. | en_US |
dc.format.extent | 1143030 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | The stereochemistry of ethylene-1,2-d2 epoxidation over silver catalysts | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationother | School of Chemistry, Macquarie University, North Ryde, New South Wales 2113, Australia | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/23136/1/0000060.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9517(80)90307-3 | en_US |
dc.identifier.source | Journal of Catalysis | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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