Bimetallic ruthenium-gold-on-magnesia catalysts: Chemicophysical properties and catalytic activity
dc.contributor.author | Bassi, I. W. | en_US |
dc.contributor.author | Garbassi, F. | en_US |
dc.contributor.author | Vlaic, G. | en_US |
dc.contributor.author | Marzi, A. | en_US |
dc.contributor.author | Tauszik, G. R. | en_US |
dc.contributor.author | Cocco, G. | en_US |
dc.contributor.author | Galvagno, S. | en_US |
dc.contributor.author | Parravano, Guiseppe | en_US |
dc.date.accessioned | 2006-04-07T17:22:50Z | |
dc.date.available | 2006-04-07T17:22:50Z | |
dc.date.issued | 1980-08 | en_US |
dc.identifier.citation | Bassi, I. W., Garbassi, F., Vlaic, G., Marzi, A., Tauszik, G. R., Cocco, G., Galvagno, S., Parravano, G. (1980/08)."Bimetallic ruthenium-gold-on-magnesia catalysts: Chemicophysical properties and catalytic activity." Journal of Catalysis 64(2): 405-416. <http://hdl.handle.net/2027.42/23184> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHJ-4CFW1B3-71/2/455ad05fd395625ee130874ccc3549b2 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/23184 | |
dc.description.abstract | Bimetallic Ru-Au catalysts supported on MgO were prepared, their atomic composition varying from 100% Ru to 100% Au. Samples were characterized after impregnation and drying at 110 [deg]C and after further reduction by hydrogen at 400 [deg]C. X-Ray line broadening analysis, small-angle X-ray scattering, transmission electron microscopy, gas chemisorption, diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), and extended X-ray absorption fine structure (EXAFS) analysis were used. Catalytic activity was measured for the oxygen transfer between CO and CO2. The Ru and Au precursor compounds appear to be modified, and have probably interacted in the bimetallic samples, already after impregnation and drying. Relevant amounts of metal oxides are found in some "reduced" catalysts; a metal-support interaction is proposed for Au/MgO. The amounts of the Ru and Au oxidized species found by EXAFS in the examined bimetallic sample are significantly different from those found in Ru/MgO and Au/MgO, respectively. The DR spectra of the bimetallic samples are not a simple combination of those of the monometallic catalysts. The Ru/Au atomic ratios measured by XPS are higher than the analytical ones. The fraction of surface Ru atoms, measured by hydrogen chemisorption, increases on decreasing the bulk Ru/Au atomic ratio. The Au/MgO sample has an activity which is two orders of magnitude higher than that of the remaining samples. All of this suggests the existence of a Ru surface enrichment and also an Ru-Au chemical interaction. These conclusions are also supported by an ir study of CO chemisorbed on the same samples. | en_US |
dc.format.extent | 970379 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Bimetallic ruthenium-gold-on-magnesia catalysts: Chemicophysical properties and catalytic activity | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109 | en_US |
dc.contributor.affiliationother | Istituto Guido Donegani S.p.A., Novara Research Center, Via Fauser 4, 28100 Novara, Italy | en_US |
dc.contributor.affiliationother | Istituto Guido Donegani S.p.A., Novara Research Center, Via Fauser 4, 28100 Novara, Italy | en_US |
dc.contributor.affiliationother | Istituto Guido Donegani S.p.A., Novara Research Center, Via Fauser 4, 28100 Novara, Italy | en_US |
dc.contributor.affiliationother | Montedison S.p.A., Bollate Research Center, Via San Pietro 50, 20021 Bollate, Milano, Italy | en_US |
dc.contributor.affiliationother | Montedison S.p.A., Bollate Research Center, Via San Pietro 50, 20021 Bollate, Milano, Italy | en_US |
dc.contributor.affiliationother | Institute of Physical Chemistry, University of Venice, D.D. 2137, 30123 Venezia, Italy | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/23184/1/0000111.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9517(80)90513-8 | en_US |
dc.identifier.source | Journal of Catalysis | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.