A spectroscopic and optically detected magnetic resonance study of PO-2 in potassium chloride. III. Photo-orientation
dc.contributor.author | Hunter, S. J. | en_US |
dc.contributor.author | Hipps, K. W. | en_US |
dc.contributor.author | Bramley, Richard | en_US |
dc.contributor.author | Francis, Anthony H. | en_US |
dc.date.accessioned | 2006-04-07T17:28:58Z | |
dc.date.available | 2006-04-07T17:28:58Z | |
dc.date.issued | 1980-01-01 | en_US |
dc.identifier.citation | Hunter, S. J., Hipps, K. W., Bramley, Richard, Francis, A. H. (1980/01/01)."A spectroscopic and optically detected magnetic resonance study of PO-2 in potassium chloride. III. Photo-orientation." Chemical Physics 45(1): 149-157. <http://hdl.handle.net/2027.42/23379> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TFM-44DTDPX-1S/2/db8e26ea4a1e6c9408b36ca069724fea | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/23379 | |
dc.description.abstract | The small molecular anion PO-2 has been incorporated at chloride ion vacancies in the potassium chloride lattice, where the relatively high symmetry of the crystal field permits a variety of crystallographically equivalent orientations of the ion within the vacancy site. Electronic excitation to the first excited singlet state of PO-2 (1B2) is followed by rapid radiationless relaxation and intersystem crossing to the phosphorescent 3B1 state. Subsequent electronic relaxation to the ground state is found to proceed with a reorientation of the ion in the multi-minimum crystal potential. At temperatures sufficiently low that competitive thermal reorientation of the ions is quenched, it is possible to prepare photo-oriented arrays of PO-2 ions in the anion vacancies by irradiation with plane polarized light at special angles. The temperature dependence of the rate of photo-orientation has been determined and it has been found possible to describe the observed kinetics in terms of a simple phenomenological rate equation. Photo-orientation-evidently results from an extraordinarily strong linear electron--phonon coupling and may be used for a detailed study of this type of interaction. The potential barrier for conversion between crystallographically equivalent sites is found to be 783 cm-1. | en_US |
dc.format.extent | 766923 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | A spectroscopic and optically detected magnetic resonance study of PO-2 in potassium chloride. III. Photo-orientation | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Physics | en_US |
dc.subject.hlbsecondlevel | Mathematics | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA; Present address: Department of Chemistry, Washington State University, Pullman WA 99164, USA. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA; On leave from Research School of Chemistry, Australian National University, Canberra, A.C.T. 2600, Australia. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/23379/1/0000324.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0301-0104(80)85177-9 | en_US |
dc.identifier.source | Chemical Physics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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