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Cyclopropane hydrogenation on Ru and Ru---Au catalysts

dc.contributor.authorGalvagno, S.en_US
dc.contributor.authorSchwank, Johannes W.en_US
dc.contributor.authorParravano, Guiseppeen_US
dc.date.accessioned2006-04-07T17:29:15Z
dc.date.available2006-04-07T17:29:15Z
dc.date.issued1980-01en_US
dc.identifier.citationGalvagno, S., Schwank, J., Parravano, G. (1980/01)."Cyclopropane hydrogenation on Ru and Ru---Au catalysts." Journal of Catalysis 61(1): 223-231. <http://hdl.handle.net/2027.42/23388>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHJ-4CFVGRV-M6/2/e24defd7f7079bac3018678d67e48f71en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/23388
dc.description.abstractThe rate of reaction between cyclopropane and hydrogen was measured in a flow system on unsupported Ru, Ru/SiO2, andRu/MgO. The effect of the addition of Au to Ru/MgO was also investigated. The temperature was in the range 30-170 [deg]C; partial pressures were 0.01 cp PH2 3H6 + H2 --&gt; C3H8, (1) cyclo-C3H6 + 2H2 --&gt; CH4 + C2H6, (2) cyclo-C3H6 + 3H2 --&gt; 3CH4. (3)At low temperatures (110 [deg]C), reaction (3) was also detected. Ruthenium particle size and presence of Au on the surface were found to have a strong influence on reaction (3), while reactions (1) and (2) were unaffected. It is suggested that, on Ru, reactions (1) and (2) have the same intermediate or they require a surface site having the same geometry.en_US
dc.format.extent709562 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleCyclopropane hydrogenation on Ru and Ru---Au catalystsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/23388/1/0000333.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0021-9517(80)90358-9en_US
dc.identifier.sourceJournal of Catalysisen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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