Cyclopropane hydrogenation on Ru and Ru---Au catalysts
dc.contributor.author | Galvagno, S. | en_US |
dc.contributor.author | Schwank, Johannes W. | en_US |
dc.contributor.author | Parravano, Guiseppe | en_US |
dc.date.accessioned | 2006-04-07T17:29:15Z | |
dc.date.available | 2006-04-07T17:29:15Z | |
dc.date.issued | 1980-01 | en_US |
dc.identifier.citation | Galvagno, S., Schwank, J., Parravano, G. (1980/01)."Cyclopropane hydrogenation on Ru and Ru---Au catalysts." Journal of Catalysis 61(1): 223-231. <http://hdl.handle.net/2027.42/23388> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHJ-4CFVGRV-M6/2/e24defd7f7079bac3018678d67e48f71 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/23388 | |
dc.description.abstract | The rate of reaction between cyclopropane and hydrogen was measured in a flow system on unsupported Ru, Ru/SiO2, andRu/MgO. The effect of the addition of Au to Ru/MgO was also investigated. The temperature was in the range 30-170 [deg]C; partial pressures were 0.01 cp PH2 3H6 + H2 --> C3H8, (1) cyclo-C3H6 + 2H2 --> CH4 + C2H6, (2) cyclo-C3H6 + 3H2 --> 3CH4. (3)At low temperatures (110 [deg]C), reaction (3) was also detected. Ruthenium particle size and presence of Au on the surface were found to have a strong influence on reaction (3), while reactions (1) and (2) were unaffected. It is suggested that, on Ru, reactions (1) and (2) have the same intermediate or they require a surface site having the same geometry. | en_US |
dc.format.extent | 709562 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Cyclopropane hydrogenation on Ru and Ru---Au catalysts | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/23388/1/0000333.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9517(80)90358-9 | en_US |
dc.identifier.source | Journal of Catalysis | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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