Thermophysical properties of the garnet, grossular: Ca3Al2Si3O12
dc.contributor.author | Westrum, Jr. , Edgar F. | en_US |
dc.contributor.author | Essene, Eric J. | en_US |
dc.contributor.author | Perkins, III, Dexter | en_US |
dc.date.accessioned | 2006-04-07T17:38:05Z | |
dc.date.available | 2006-04-07T17:38:05Z | |
dc.date.issued | 1979-01 | en_US |
dc.identifier.citation | Westrum, Jr., Edgar F., Essene, Eric J., Perkins, III, Dexter (1979/01)."Thermophysical properties of the garnet, grossular: Ca3Al2Si3O12." The Journal of Chemical Thermodynamics 11(1): 57-66. <http://hdl.handle.net/2027.42/23666> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4CRH8RR-2V/2/800ad908a8d4fe82393b4d40eea1a346 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/23666 | |
dc.description.abstract | The heat capacity of a gem-quality mineralogical sample of grossular: Ca3Al2Si3O12 has been determined by equilibrium adiabatic-shield calorimetry from 5 through 600 K and adjusted to the stoichiometric terminal-component grossular by a new entropy-adjustment scheme delineated in the paper. At 298.15 K the observed values of Cp, So, {Ho(T)-Ho(0)}/T, and -{Go(T)-Ho(0)}/T are 79.00, 61.61, 37.92, and 23.69 calth K-1 mol-1. The entropy adjusted to terminal component grossular is 60.88 calth K-1 mol-1. The results are combined with higher-temperature differential-scanning calorimetric values of Perkins et al. and of Robie et al. to provide thermodynamic values over greatly extended ranges of temperature. | en_US |
dc.format.extent | 618929 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Thermophysical properties of the garnet, grossular: Ca3Al2Si3O12 | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Geology and Mineralogy, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Geology and Mineralogy, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/23666/1/0000634.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9614(79)90083-1 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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