View Item 

Show simple item record

Thermophysical properties of the garnet, grossular: Ca3Al2Si3O12
dc.contributor.authorWestrum, Jr. , Edgar F.en_US
dc.contributor.authorEssene, Eric J.en_US
dc.contributor.authorPerkins, III, Dexteren_US
dc.date.accessioned2006-04-07T17:38:05Z
dc.date.available2006-04-07T17:38:05Z
dc.date.issued1979-01en_US
dc.identifier.citationWestrum, Jr., Edgar F., Essene, Eric J., Perkins, III, Dexter (1979/01)."Thermophysical properties of the garnet, grossular: Ca3Al2Si3O12." The Journal of Chemical Thermodynamics 11(1): 57-66. <http://hdl.handle.net/2027.42/23666>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHM-4CRH8RR-2V/2/800ad908a8d4fe82393b4d40eea1a346en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/23666
dc.description.abstractThe heat capacity of a gem-quality mineralogical sample of grossular: Ca3Al2Si3O12 has been determined by equilibrium adiabatic-shield calorimetry from 5 through 600 K and adjusted to the stoichiometric terminal-component grossular by a new entropy-adjustment scheme delineated in the paper. At 298.15 K the observed values of Cp, So, {Ho(T)-Ho(0)}/T, and -{Go(T)-Ho(0)}/T are 79.00, 61.61, 37.92, and 23.69 calth K-1 mol-1. The entropy adjusted to terminal component grossular is 60.88 calth K-1 mol-1. The results are combined with higher-temperature differential-scanning calorimetric values of Perkins et al. and of Robie et al. to provide thermodynamic values over greatly extended ranges of temperature.en_US
dc.format.extent618929 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThermophysical properties of the garnet, grossular: Ca3Al2Si3O12en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Geology and Mineralogy, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Geology and Mineralogy, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/23666/1/0000634.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0021-9614(79)90083-1en_US
dc.identifier.sourceThe Journal of Chemical Thermodynamicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


Files in this item

Name:
0000634.pdf
Size:
604.4KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.