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The microwave spectrum and structure of propylene oxide
dc.contributor.authorImachi, Misakoen_US
dc.contributor.authorKuczkowski, Robert L.en_US
dc.date.accessioned2006-04-07T17:45:17Z
dc.date.available2006-04-07T17:45:17Z
dc.date.issued1982-12en_US
dc.identifier.citationImachi, M., Kuczkowski, R. L. (1982/12)."The microwave spectrum and structure of propylene oxide." Journal of Molecular Structure 96(1-2): 55-60. <http://hdl.handle.net/2027.42/23774>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGS-4933SKP-8/2/b635f9582447209270533e6df0a18170en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/23774
dc.description.abstractThe rs and ro structural parameters have been determined for propylene oxide from rotational constants for 16 isotopic species. The heavy-atom (ro) parameters are : r(C1C2) = 1.470(3), r(C2C3) = 1.505(2), r(C1O) = 1.441(2), r(C2O) = 1.435(3) A, [angle] OC2C2 = 59.1(2), [angle]OC2C1 = 59.4(1), [angle]C1OC2 = 61.5(2), [angle]C1C2C3 = 121.7(2), [angle]C2C3 = 116.1(2)[deg]. The methyl group torsional angles with the ring are: [tau](C1C2C3H9) = 24.7(8) and [tau](OC2C3H9) = -44.0[deg](5). These parameters agree closely with analogous results for ethylene oxide.en_US
dc.format.extent465978 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThe microwave spectrum and structure of propylene oxideen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/23774/1/0000012.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-2860(82)90057-6en_US
dc.identifier.sourceJournal of Molecular Structureen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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