Metal complex-catalyzed redistribution reactions of organosilanes : IV. Redistribution reactions of methylsiloxanes catalyzed by transition metal complexes
dc.contributor.author | Gustavson, Wayne A. | en_US |
dc.contributor.author | Epstein, Paul S. | en_US |
dc.contributor.author | Curtis, M. David | en_US |
dc.date.accessioned | 2006-04-07T17:47:10Z | |
dc.date.available | 2006-04-07T17:47:10Z | |
dc.date.issued | 1982-10-19 | en_US |
dc.identifier.citation | Gustavson, Wayne A., Epstein, Paul S., Curtis, M. D. (1982/10/19)."Metal complex-catalyzed redistribution reactions of organosilanes : IV. Redistribution reactions of methylsiloxanes catalyzed by transition metal complexes." Journal of Organometallic Chemistry 238(1): 87-97. <http://hdl.handle.net/2027.42/23830> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGW-433PN40-4K/2/d4430a75436498459b5eb0a73e80d8c1 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/23830 | |
dc.description.abstract | Redistribution reactions of a variety of hydrogen-substituted siloxanes are catalyzed by various transition metal complexes of iridium and rhodium. The products arise from breaking and remaking of Si---C, Si---H, and Si---O bonds. Siloxanes not possessing a Si---H bond are inert under the conditions studied. The most favored reaction pathway appears to scramble preferentially the groups directly attached to the silicon bearing the hydrogen atom. A new cyclo-iridiadisiloxane, L2(CO)(H)IiMeR) (L = Ph3P; R = Me3SiO) is reported. This compound exists in three isomeric forms as a consequence of the spatial arrangements of the R and Me groups on the ring. | en_US |
dc.format.extent | 818063 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Metal complex-catalyzed redistribution reactions of organosilanes : IV. Redistribution reactions of methylsiloxanes catalyzed by transition metal complexes | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109 U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109 U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, MI 48109 U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/23830/1/0000069.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/S0022-328X(00)86840-0 | en_US |
dc.identifier.source | Journal of Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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