Spectrophotometric investigation of products formed following the initial one-electron electrochemical reduction of nicotinamide adenine dinucleotide (NAD+)
dc.contributor.author | Bresnahan, William T. | en_US |
dc.contributor.author | Elving, Philip Juliber | en_US |
dc.date.accessioned | 2006-04-07T17:58:47Z | |
dc.date.available | 2006-04-07T17:58:47Z | |
dc.date.issued | 1981-12-04 | en_US |
dc.identifier.citation | Bresnahan, William T., Elving, Philip J. (1981/12/04)."Spectrophotometric investigation of products formed following the initial one-electron electrochemical reduction of nicotinamide adenine dinucleotide (NAD+)." Biochimica et Biophysica Acta (BBA) - General Subjects 678(2): 151-156. <http://hdl.handle.net/2027.42/24167> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6T1W-47MCKJ4-1/2/143e227d2044c0da3fc038c6cc7b182c | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/24167 | |
dc.identifier.uri | http://www.ncbi.nlm.nih.gov/sites/entrez?cmd=retrieve&db=pubmed&list_uids=7317445&dopt=citation | en_US |
dc.description.abstract | On electrolysis of NAD+ in aqueous solution at a potential corresponding to the initial one-electron reduction of NAD+ to a free radical, a greenish-yellow color appears which fades when electrolysis is complete. Literature ultraviolet absorption data for the resulting dimer show considerable variation. When the electrolysis is conducted in darkness, the colored product has [epsilon]340 of approx. 5700 M-1 [middle dot] cm-1 and [epsilon]259 of approx. 31000 M-1 [middle dot] cm-1. On ultraviolet and visible illumination, the color disappears, the 340-nm peak decreases and the 259-nm peak increases. On only visible illumination, the color disappears, both peaks increases, the dimer's polarographic oxidation wave decreases and the wave due to 1-substituted nicotinamide reduction increases. The data suggest that the dimer decomposes to NAD+ and 1,4-NADH. | en_US |
dc.format.extent | 468494 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Spectrophotometric investigation of products formed following the initial one-electron electrochemical reduction of nicotinamide adenine dinucleotide (NAD+) | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan Ann Arbor, MI 48109, U.S.A. | en_US |
dc.identifier.pmid | 7317445 | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/24167/1/0000425.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0304-4165(81)90200-2 | en_US |
dc.identifier.source | Biochimica et Biophysica Acta | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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