Dissolution kinetics: Catalysis by strong acids
dc.contributor.author | Kline, W. E. | en_US |
dc.contributor.author | Fogler, H. Scott | en_US |
dc.date.accessioned | 2006-04-07T18:04:12Z | |
dc.date.available | 2006-04-07T18:04:12Z | |
dc.date.issued | 1981-07 | en_US |
dc.identifier.citation | Kline, W. E., Fogler, H. S. (1981/07)."Dissolution kinetics: Catalysis by strong acids." Journal of Colloid and Interface Science 82(1): 93-102. <http://hdl.handle.net/2027.42/24319> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHR-4CV9429-31/2/4ced0385e0c67badb7f1bb7281023cac | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/24319 | |
dc.description.abstract | The dissolution of silicate minerals in mixtures of hydrofluoric acid and strong acids such as HCl is catalyzed by H+ ions adsorbed at the mineral surface. Studies of the catalyzed dissolution of kaolinite, quartz, potassium feldspar, and sodium montmorillonite have shown that the rates of dissolution can be increased by as much as 900%. The dissolution process can be modeled as simultaneous catalyzed and uncatalyzed reactions, where the surface concentration of H+ ions is determined by a Langmuir adsorption isotherm. The degree of catalysis is a strong function of the nature of the silicate surface, a fact which has application in the area of selective dissolution within mixed mineral systems. | en_US |
dc.format.extent | 681924 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Dissolution kinetics: Catalysis by strong acids | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, The University of Michigan, Ann Arbor, Michigan 48109, USA | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, The University of Michigan, Ann Arbor, Michigan 48109, USA | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/24319/1/0000586.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9797(81)90127-2 | en_US |
dc.identifier.source | Journal of Colloid and Interface Science | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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