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A theoretical study of the gas-phase basicity of molecules containing arsenic--carbon multiple bonds
dc.contributor.authorLohr, Lawrence L. Jr.en_US
dc.contributor.authorScheiner, Andrew C.en_US
dc.date.accessioned2006-04-07T18:26:06Z
dc.date.available2006-04-07T18:26:06Z
dc.date.issued1984-07en_US
dc.identifier.citationLohr, Lawrence L., Scheiner, Andrew C. (1984/07)."A theoretical study of the gas-phase basicity of molecules containing arsenic--carbon multiple bonds." Journal of Molecular Structure: THEOCHEM 109(3-4): 195-200. <http://hdl.handle.net/2027.42/24764>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGT-44GR78R-MS/2/d0343f7789e6d768f5bea9e7d138db5ben_US
dc.identifier.urihttps://hdl.handle.net/2027.42/24764
dc.description.abstractGas-phase proton affinities are calculated using ab initio methods for the unknown unsaturated molecules H2CAsH and HCAs as well as for AsH3. The results parallel those previously found by us for the corresponding phosphorus compounds, in that the order of basicities is AsH3 &gt; H2CAsH&gt; HCAs. For H2CAsH the C-site and As-site PA's are nearly equal, while for HCAs protonation is predicted to occur only at C.en_US
dc.format.extent475766 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleA theoretical study of the gas-phase basicity of molecules containing arsenic--carbon multiple bondsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/24764/1/0000187.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0166-1280(84)80003-2en_US
dc.identifier.sourceJournal of Molecular Structure: THEOCHEMen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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