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Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates

dc.contributor.authorFranzosini, P.en_US
dc.contributor.authorWestrum, Jr. , Edgar F.en_US
dc.date.accessioned2006-04-07T18:33:04Z
dc.date.available2006-04-07T18:33:04Z
dc.date.issued1984-01en_US
dc.identifier.citationFranzosini, P., Westrum, Jr., Edgar F. (1984/01)."Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates." The Journal of Chemical Thermodynamics 16(1): 81-90. <http://hdl.handle.net/2027.42/24959>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHM-4CRHB2C-RB/2/272cbab5b07e6929e3ef6080be163089en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/24959
dc.description.abstractAt 298.15 K, the values of Cp, m/R, Smo/R, {Hmo - Hmo(0)}/R, and {Gmo - Hmo(0)}/RT ar 15.58, 17.13, 2588.6 K, and -8.445 for CH3CH2CO2Li(cr), and 17.30, 21.16, 3134.0 K, and -10.647 for CH3CH2CO2K(cr). The energetics and shape of the (crystal III-to-crystal II) transition at Ttrs = 255 K in the potassium compound are investigated. The lithium compound showed a (crystal II-to-crystal I) transition not far above 500 K, and fusion at 606.8 K. Relative trends in the Li, Na, and K salts are unexplained because of lack of structural information.en_US
dc.format.extent557454 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoatesen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/24959/1/0000386.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0021-9614(84)90078-8en_US
dc.identifier.sourceThe Journal of Chemical Thermodynamicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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