Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates
dc.contributor.author | Franzosini, P. | en_US |
dc.contributor.author | Westrum, Jr. , Edgar F. | en_US |
dc.date.accessioned | 2006-04-07T18:33:04Z | |
dc.date.available | 2006-04-07T18:33:04Z | |
dc.date.issued | 1984-01 | en_US |
dc.identifier.citation | Franzosini, P., Westrum, Jr., Edgar F. (1984/01)."Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates." The Journal of Chemical Thermodynamics 16(1): 81-90. <http://hdl.handle.net/2027.42/24959> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4CRHB2C-RB/2/272cbab5b07e6929e3ef6080be163089 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/24959 | |
dc.description.abstract | At 298.15 K, the values of Cp, m/R, Smo/R, {Hmo - Hmo(0)}/R, and {Gmo - Hmo(0)}/RT ar 15.58, 17.13, 2588.6 K, and -8.445 for CH3CH2CO2Li(cr), and 17.30, 21.16, 3134.0 K, and -10.647 for CH3CH2CO2K(cr). The energetics and shape of the (crystal III-to-crystal II) transition at Ttrs = 255 K in the potassium compound are investigated. The lithium compound showed a (crystal II-to-crystal I) transition not far above 500 K, and fusion at 606.8 K. Relative trends in the Li, Na, and K salts are unexplained because of lack of structural information. | en_US |
dc.format.extent | 557454 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/24959/1/0000386.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9614(84)90078-8 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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