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Surface enhanced raman spectroscopy of halide ions on colloidal silver: morphology and coverage dependence
dc.contributor.authorGarrell, Robin L.en_US
dc.contributor.authorShaw, Keith D.en_US
dc.contributor.authorKrimm, Samuelen_US
dc.date.accessioned2006-04-07T18:46:35Z
dc.date.available2006-04-07T18:46:35Z
dc.date.issued1983-01-02en_US
dc.identifier.citationGarrell, Robin L., Shaw, Keith D., Krimm, S. (1983/01/02)."Surface enhanced raman spectroscopy of halide ions on colloidal silver: morphology and coverage dependence." Surface Science 124(2-3): 613-624. <http://hdl.handle.net/2027.42/25327>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TVX-47KR2M4-12/2/ab36f01b8e78723c5ad85710876a4a12en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/25327
dc.description.abstractTransmission electron microscopy shows that the colloidal silver used as a substrate for surface enhanced Raman spectroscopy consists of 75-135 A average diameter faceted crystals, which can be made to aggregate in clusters of few to thousands of particles. Aggregates are not required for observation of the SER spectrum of adsorbed halide ions or pyridine. Bromide is shown to adsorb more readily than chloride, and in time it displaces chloride on the silver surface. Spectra of halide ions adsorbed on sols with various particle morphologies lend additional support to our interacting dipole model describing the origins of the spectral band fine structure.en_US
dc.format.extent896531 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleSurface enhanced raman spectroscopy of halide ions on colloidal silver: morphology and coverage dependenceen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Physics and Macromolecular Research Center, The University of Michigan, Ann Arbon, Michigan 48109, USAen_US
dc.contributor.affiliationumDepartment of Physics and Macromolecular Research Center, The University of Michigan, Ann Arbon, Michigan 48109, USAen_US
dc.contributor.affiliationumDepartment of Physics and Macromolecular Research Center, The University of Michigan, Ann Arbon, Michigan 48109, USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/25327/1/0000772.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0039-6028(83)90815-4en_US
dc.identifier.sourceSurface Scienceen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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