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Synthesis and resolution of substituted pipecolic acids
dc.contributor.authorOverberger, Charles Gilberten_US
dc.contributor.authorShalati, Mohamad D.en_US
dc.date.accessioned2006-04-07T18:51:02Z
dc.date.available2006-04-07T18:51:02Z
dc.date.issued1983en_US
dc.identifier.citationOverberger, C. G., Shalati, M. D. (1983)."Synthesis and resolution of substituted pipecolic acids." European Polymer Journal 19(10-11): 1055-1065. <http://hdl.handle.net/2027.42/25448>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TWW-48CXS9N-9G/2/07357a8a9434ff10320afeb8ee94b081en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/25448
dc.description.abstractA new general method for the preparation of 2-alkyl-pipecolic acids has been developed. The syntheses of 2-methyl-, 2-benzyl- and cis-6-methylpipecolic acids are described. (-)S- and (+)R-2-methylpipecolic acids were resolved by fractional crystallization of the quinine salt of their N-carbobenzoxy derivative. Isolation of (-)S-cis-6-methylpipecolic acid required the use of 4-phenylbenzyloxycarbonyl as protecting group to achieve selective crystallization of the quinine salt. The absolute configurations of these compounds were determined by circular dichroism.en_US
dc.format.extent825524 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleSynthesis and resolution of substituted pipecolic acidsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor, MI 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry and the Macromolecular Research Center, The University of Michigan, Ann Arbor, MI 48109, U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/25448/1/0000898.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0014-3057(83)90072-1en_US
dc.identifier.sourceEuropean Polymer Journalen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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