Thermodynamics of thallium alkanoates I. Heat capacity and thermodynamic functions of thallium(I) n-hexanoate
dc.contributor.author | Boerio-Goates, Juliana | en_US |
dc.contributor.author | Lopez de la Fuente, F. L. | en_US |
dc.contributor.author | Cheda, Jose A. R. | en_US |
dc.contributor.author | Westrum, Jr. , Edgar F. | en_US |
dc.date.accessioned | 2006-04-07T19:05:30Z | |
dc.date.available | 2006-04-07T19:05:30Z | |
dc.date.issued | 1985-05 | en_US |
dc.identifier.citation | Boerio-Goates, Juliana, Lopez de la Fuente, F. L., Cheda, Jose A. R., Westrum, Jr., Edgar F. (1985/05)."Thermodynamics of thallium alkanoates I. Heat capacity and thermodynamic functions of thallium(I) n-hexanoate." The Journal of Chemical Thermodynamics 17(5): 401-408. <http://hdl.handle.net/2027.42/25683> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4CX6M91-1/2/6eec4b42c3a13f40039dc55a96c2b1ca | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/25683 | |
dc.description.abstract | The sub-ambient heat capacity of thallium(I) n-hexanoate is characterized by transitions at 203.5 and 208.3 K which show Cp, m/R maxima of about 400 and 2500 and ([Delta]Sm/R)'s of 1.03 and 1.07. Both appear to be essentially first order and show typical under-cooling phenomena. The heat capacities are in excellent accord with the d.s.c. values of Fernandez-Martin, Lopez de la Fuente, and Cheda over the common range of super-ambient values. At T = 298.15 K the values of {Smo(T)-Smo(0)}/R, {Hmo(T)-Hmo(0)}/R, and -{Gmo(T)-Hmo(0)}/RT are 39.06, 5880 K, and 19.33. Smoothed thermodynamic functions are tabulated through melting. | en_US |
dc.format.extent | 416385 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Thermodynamics of thallium alkanoates I. Heat capacity and thermodynamic functions of thallium(I) n-hexanoate | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/25683/1/0000237.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9614(85)90137-5 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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