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Thermodynamics of uranium intermetallic compounds I. Heat capacities of URu3 and URh3 from 5 to 850 K
dc.contributor.authorCordfunke, E. H. P.en_US
dc.contributor.authorMuis, R. P.en_US
dc.contributor.authorWijbenga, G.en_US
dc.contributor.authorBurriel, Ramonen_US
dc.contributor.authorTo, Michael Wing Keien_US
dc.contributor.authorZainel, Hannaen_US
dc.contributor.authorWestrum, Jr. , Edgar F.en_US
dc.date.accessioned2006-04-07T19:16:11Z
dc.date.available2006-04-07T19:16:11Z
dc.date.issued1985-11en_US
dc.identifier.citationCordfunke, E. H. P., Muis, R. P., Wijbenga, G., Burriel, Ramon, To, Michael Wing Kei, Zainel, Hanaa, Westrum, Jr., Edgar F. (1985/11)."Thermodynamics of uranium intermetallic compounds I. Heat capacities of URu3 and URh3 from 5 to 850 K." The Journal of Chemical Thermodynamics 17(11): 1035-1044. <http://hdl.handle.net/2027.42/25929>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHM-4CRHBN7-R3/2/d1610b7d0a1e3b87dddebdb8fe4879f1en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/25929
dc.description.abstractHeat capacities of carefully characterized samples of URu3 and URh3 were measured by adiabatic calorimetry from 5 to 350 K by adiabatic calorimetry and from 300 to 850 K by enthalpy-increment drop calorimetry. Values for the thermodynamic properties at 298.15 K; Cp,m/R, Smo/R, {Hmo(T)-Hmo}(0)/R, and -{Gmo(T)-Hmo(0)}/R are: URu3: 12.20, 17.38, 2550 K, and 8.82 K; URh3: 12.39, 18.31, 2639 K, and 9.46 K. Phase transitions were not observed over the entire temperature range. In contrast with UPd3 with localized spins and with related materials showing localized spin fluctuations, the electronic coefficients show typical metallic behavior.en_US
dc.format.extent713181 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThermodynamics of uranium intermetallic compounds I. Heat capacities of URu3 and URh3 from 5 to 850 Ken_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, U.S.A.en_US
dc.contributor.affiliationotherNetherlands Energy Research Foundation ECN, Petten (NH), The Netherlandsen_US
dc.contributor.affiliationotherNetherlands Energy Research Foundation ECN, Petten (NH), The Netherlandsen_US
dc.contributor.affiliationotherNetherlands Energy Research Foundation ECN, Petten (NH), The Netherlandsen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/25929/1/0000492.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0021-9614(85)90088-6en_US
dc.identifier.sourceThe Journal of Chemical Thermodynamicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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