The heat capacity of a natural monticellite and phase equilibria in the system CaO-MgO-SiO2-CO2
dc.contributor.author | Sharp, Z. D. | en_US |
dc.contributor.author | Essene, Eric J. | en_US |
dc.contributor.author | Anovitz, Lawrence M. | en_US |
dc.contributor.author | Metz, Guy W. | en_US |
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.contributor.author | Hemingway, Bruce S. | en_US |
dc.contributor.author | Valley, John W. | en_US |
dc.date.accessioned | 2006-04-07T19:29:40Z | |
dc.date.available | 2006-04-07T19:29:40Z | |
dc.date.issued | 1986-07 | en_US |
dc.identifier.citation | Sharp, Z. D., Essene, E. J., Anovitz, L. M., Metz, G. W., Westrum, Jr., E. F., Hemingway, B. S., Valley, J. W. (1986/07)."The heat capacity of a natural monticellite and phase equilibria in the system CaO-MgO-SiO2-CO2." Geochimica et Cosmochimica Acta 50(7): 1475-1484. <http://hdl.handle.net/2027.42/26132> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6V66-488Y31V-FR/2/9f315e7d1f239fdc0432590124aca1a7 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/26132 | |
dc.description.abstract | The heat capacity of a natural monticellite (Ca1.00Mg.09Fe.91Mn.01Si0.99O3.99) measured between 9.6 and 343 K using intermittent-heating, adiabatic calorimetry yields Cp0(298) and S2980 of 123.64 +/- 0.18 and 109.44 +/- 0.16 J [middle dot] mol-1 K-1 respectively. Extrapolation of this entropy value to end-member monticellite results in an S0298 = 108.1 +/- 0.2 J [middle dot] mol-1 K-1. High-temperature heat-capacity data were measured between 340-1000 K with a differential scanning calorimeter. The high-temperature data were combined with the 290-350 K adiabatic values, extrapolated to 1700 K, and integrated to yield the following entropy equation for end-member monticellite (298-1700 K): ST0(J [middle dot] mol-1 K-1) = S2980 + 164.79 In T + 15.337 [middle dot] 10-3 T + 22.791 [middle dot] 105 T-2 - 968.94. Phase equilibria in the CaO-MgO-SiO2 system were calculated from 973 to 1673 K and 0 to 12 kbar with these new data combined with existing data for akermanite (Ak), diopside (Di), forsterite (Fo), merwinite (Me) and wollastonite (Wo). The location of the calculated reactions involving the phases Mo and Fo is affected by their mutual solid solution. A best fit of the thermodynamically generated curves to all experiments is made when the S0298 of Me is 250.2 J [middle dot] mol-1 K-1 less than the measured value of 253.2 J [middle dot] mol-1 K-1.A best fit to the reversals for the solid-solid and decarbonation reactions in the CaO-MgO-SiO2-CO2 system was obtained with the [Delta]G0298 (kJ [middle dot] mole-1) for the phases Ak(-3667), Di(-3025), Fo(-2051), Me(-4317) and Mo(-2133). The two invariant points - Wo and -Fo for the solid-solid reactions are located at 1008 +/- 5 K and 6.3 +/- 0.1 kbar, and 1361 +/- 10 K and 10.2 +/- 0.2 kbar respectively. The location of the thermodynamically generated curves is in excellent agreement with most experimental data on decarbonation equilibria involving these phases. | en_US |
dc.format.extent | 1236548 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | The heat capacity of a natural monticellite and phase equilibria in the system CaO-MgO-SiO2-CO2 | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Geology and Earth Sciences | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Geological Sciences, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationother | United States Geological Survey, 959 National Center, Reston, VA 22092, U.S.A. | en_US |
dc.contributor.affiliationother | Department of Geology and Geophysics, University of Wisconsin, Madison, WI 53706, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/26132/1/0000208.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0016-7037(86)90321-2 | en_US |
dc.identifier.source | Geochimica et Cosmochimica Acta | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.