View Item 

Show simple item record

1,1'-trimethylenebisthymine as synthetic model of dinucleotide TpT Electrochemical reduction
dc.contributor.authorMalinski, Tadeuszen_US
dc.contributor.authorLanger, Jerzy J.en_US
dc.contributor.authorMoiroux, Jacquesen_US
dc.contributor.authorElving, Philip Juliberen_US
dc.date.accessioned2006-04-07T19:31:43Z
dc.date.available2006-04-07T19:31:43Z
dc.date.issued1986-04-25en_US
dc.identifier.citationMalinski, Tadeusz, Langer, Jerzy J., Moiroux, Jacques, Elving, Philip J. (1986/04/25)."1,1'-trimethylenebisthymine as synthetic model of dinucleotide TpT Electrochemical reduction." Journal of Electroanalytical Chemistry 201(2): 329-345. <http://hdl.handle.net/2027.42/26190>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGB-44YXMJH-DG/2/b72279694ba96d28f66881f023389a11en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/26190
dc.description.abstractThe electrochemical reduction of 1,1'-trimethylenebisthymine (Thy(C3)Thy) in dimethylsulfoxide was investigated using dc polarography, cyclic voltammetry, controlled potential electrolysis and spectroelectrochemistry. Thy(C3)Thy is reduced in a two-election step (E1/2 = -2.40 V) to a diradical dianion which abstracts protons from the parent Thy(C3)Thy to form a neutral free diradical and the Thy(C3)Thy dianion. The neutral free diradical is further reduced and protonated to form 1,1'-trimethylenebisdihydrothymine. The dianion forms insoluble mercury salts producing up to three oxidation peaks (Epa between -0.35 and -0.07V). The effect of added base on the electrochemical and spectroelectrochemical behavior is described. The number of layers of the mercury- Thy(C3)Thy salt adsorbed in the anodic and stripped in the cathodic processes was calculated. The mechanism of adsorption is discussed.en_US
dc.format.extent1044318 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.title1,1'-trimethylenebisthymine as synthetic model of dinucleotide TpT Electrochemical reductionen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109 U.S.A.en_US
dc.contributor.affiliationotherDepartment of Chemistry, Oakland University, Rochester, MI 48063 U.S.A.en_US
dc.contributor.affiliationotherDepartment of Chemistry, Oakland University, Rochester, MI 48063 U.S.A.en_US
dc.contributor.affiliationotherLab. Chimie Analitique, U.A. C.N.R.S. No. 484, Fac. Pharmacie, Université Paris V, 4 Ave. Observatoire, 75270 Paris Cedex 06 Franceen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/26190/1/0000269.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-0728(86)80058-4en_US
dc.identifier.sourceJournal of Electroanalytical Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


Files in this item

Name:
0000269.pdf
Size:
1019.KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.