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The exchange reaction of tetramethyl-diphosphine, -diarsine, -distibine and -dibismuthine

dc.contributor.authorAshe, Arthur J. IIIen_US
dc.contributor.authorLudwig Jr. , Edward G.en_US
dc.date.accessioned2006-04-07T19:32:03Z
dc.date.available2006-04-07T19:32:03Z
dc.date.issued1986-04-08en_US
dc.identifier.citationAshe, III, Arthur J., Ludwig, Jr., Edward G. (1986/04/08)."The exchange reaction of tetramethyl-diphosphine, -diarsine, -distibine and -dibismuthine." Journal of Organometallic Chemistry 303(2): 197-204. <http://hdl.handle.net/2027.42/26200>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-43B98FR-11/2/6988dde6f899adc652575c3bb29bd165en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/26200
dc.description.abstractTetramethyldiphosphine and tetramethyldiarsine undergo an exchange reaction to give (dimethylarsino)dimethylphosphine. The equilibrium constant at 25[deg]C in benzene is found to be 0.26. Similarly, mixtures of tetramethyldistibine with tetramethyldiarsine or tetramethyldibismuthine are partially converted to (dimethylarsino)dimethylstibine or (dimethylbismuthino)dimethylstibine, respectively. The thermochromic arsinostibine, 1-(2,5-dimethylarsolo)-2,5-dimethylstibole, has been prepared by a similar reaction.en_US
dc.format.extent530544 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleThe exchange reaction of tetramethyl-diphosphine, -diarsine, -distibine and -dibismuthineen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/26200/1/0000279.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-328X(86)80131-0en_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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