CO hydrogenation on Ru/Al2O3: Selectivity under transient conditions
dc.contributor.author | Zhou, X. | en_US |
dc.contributor.author | Gulari, Erdogan | en_US |
dc.date.accessioned | 2006-04-07T19:52:56Z | |
dc.date.available | 2006-04-07T19:52:56Z | |
dc.date.issued | 1987-06 | en_US |
dc.identifier.citation | Zhou, X., Gulari, Erdogan (1987/06)."CO hydrogenation on Ru/Al2O3: Selectivity under transient conditions." Journal of Catalysis 105(2): 499-510. <http://hdl.handle.net/2027.42/26696> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHJ-4CFV96V-18T/2/da4d00bf01e7dea254c2fa1f533290ca | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/26696 | |
dc.description.abstract | Transient response and isotopic tracer techniques were used to investigate the surface coverages of the reactants and the selectivity of ruthenium/alumina catalysts in CO hydrogenation. Two forms of carbon--active carbidic carbon, C[alpha], and hydrogen-containing alkylic carbon, C[beta]--are found to be present on the catalyst surface. Approximately 0.1 monolayer of C[alpha] is deposited on the catalyst through the dissociative chemisorption of CO. C[beta] is formed only in the presence of hydrogen. Unlike C[alpha], the amount of C[beta] on the catalyst surface is found to increase continuously. Under varying partial pressures of CO and H2 the surface coverage of C[alpha] changes much less than the overall rate of reaction. In addition to C[alpha] and C[beta], the catalyst surface also contained approximately 0.7 monolayer of CO and 0.1 to 0.2 monolayer of inactive carbon. Measurements of product distributions of C[alpha] and C[beta] during the hydrogen titration transients show that for C[alpha] the Schultz-Flory distribution is obeyed. In contrast, C[beta] products do not follow the same distribution. The relative selectivities of the two species of carbon during hydrogen titration transients were very different. C[beta] titration produced normal and branched alkanes in comparable amounts. No alkene is produced from C[beta]. C[alpha] titration produced primarily normal alkenes and alkanes. Our results also show that the chain propagation step is much faster than the other steps in hydrocarbon synthesis (Fischer-Tropsch synthesis) and that CO dissociation is not the rate-limiting step. | en_US |
dc.format.extent | 1023299 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | CO hydrogenation on Ru/Al2O3: Selectivity under transient conditions | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Chemical Engineering Department, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Chemical Engineering Department, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/26696/1/0000244.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9517(87)90077-7 | en_US |
dc.identifier.source | Journal of Catalysis | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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