Thermophysics of thallium alkanoates IV. Heat capacity and thermodynamic functions of thallium(I) n-dodecanoate from 7 to 470 K,
dc.contributor.author | Lopez de la Fuente, F. L. | en_US |
dc.contributor.author | Westrum, Edgar F. Jr. | en_US |
dc.contributor.author | Cheda, Jose A. R. | en_US |
dc.contributor.author | Fernandez-Martin, F. | en_US |
dc.date.accessioned | 2006-05-10T15:37:59Z | |
dc.date.available | 2006-05-10T15:37:59Z | |
dc.date.issued | 1987-12 | en_US |
dc.identifier.citation | Lopez de la Fuente, F. L., Westrum, Jr., E. F., Cheda, J. A. R., Fernandez-Martin, F. (1987/12)."Thermophysics of thallium alkanoates IV. Heat capacity and thermodynamic functions of thallium(I) n-dodecanoate from 7 to 470 K,." The Journal of Chemical Thermodynamics 19(12): 1261-1270. <http://hdl.handle.net/2027.42/27004> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4CRHDXT-1N0/2/a9fdf5a879519ff243e5ed40953c24e0 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/27004 | |
dc.description.abstract | The thermal behavior of thallium(I) n-dodecanoate was studied by adiabatic calorimetry from 6 to 350 K and by d.s.c. from 230 through 470 K. The agreement between the results (temperature and thermal functions of transitions and heat capacity) from both methods was within the experimental error over the common temperature range. Several phases were observed in the sample. Four of the five solid-to-solid transitions appeared in the common temperature range of both techniques. The two lowest-temperature transitions appear as a bifurcated pair (at 282.65 and 284.8 K) with (Cp,m/R) [approximate] 250 and 450, respectively. The third and fourth occur at 293.1 and 312.1 K with (Cpm/R) [approximate] 250 and 14000. Above 350 K three more transitions were measured by d.s.c.: solid-to-solid, solid-to-mesophase, and mesophase, and mesophase-to-isotropic-liquid transformations at 356.6, 400.1, and 471.5 K. The corresponding values of [Delta]trsSmo/R for the seven transitionswere 0.910, 1.111, 0.710, 2.075, 0.69, 1.64, and 0.50. Smoothed thermodynamic values are tabulated at selected temperatures through the "clearing" point. | en_US |
dc.format.extent | 27244 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.extent | 616376 bytes | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | text/plain | |
dc.format.mimetype | application/pdf | |
dc.language.iso | en_US | en_US |
dc.publisher | Elsevier | en_US |
dc.title | Thermophysics of thallium alkanoates IV. Heat capacity and thermodynamic functions of thallium(I) n-dodecanoate from 7 to 470 K, | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistr,v, University qf Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistr,v, University qf Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationother | Departamento de Quimica Fisica. Facultad de Ciencias Quimicas,Universidad Complutense. 28040 Madrid. Spain | en_US |
dc.contributor.affiliationother | Institute de1 Frio. C.S.I.C., 28040 Madrid, Spain | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/27004/3/0000571.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9614(87)90003-6 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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