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Thermodynamics of copper sulfides III. Heat capacities and thermodynamic properties of Cu1.75S, Cu1.80S, and Cu1.85S from 5 to about 700 K

dc.contributor.authorGronvold, Fredriken_US
dc.contributor.authorStolen, Sveinen_US
dc.contributor.authorWestrum, Jr. , Edgar F.en_US
dc.contributor.authorGaleas, Charles G.en_US
dc.date.accessioned2006-05-10T15:42:38Z
dc.date.available2006-05-10T15:42:38Z
dc.date.issued1987-12en_US
dc.identifier.citationGronvold, Fredrik, Stolen, Svein, Westrum, Jr., Edgar F., Galeas, Charles G. (1987/12)."Thermodynamics of copper sulfides III. Heat capacities and thermodynamic properties of Cu1.75S, Cu1.80S, and Cu1.85S from 5 to about 700 K." The Journal of Chemical Thermodynamics 19(12): 1305-1324. <http://hdl.handle.net/2027.42/27005>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6WHM-4CRHDXT-1N5/2/9436e771815b7bd3edcbd1cc4bea5a14en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/27005
dc.description.abstractThe heat capacities of Cu1.75S, Cu1.80S, and Cu1.85S have been measured by adiabatic-shield calorimetry from 5 to about 700 K. The heat-capacity curves show transitions near 312, 337, and 355 K in Cu1.75S and Cu1.80S and near 312, 368, and 376 K in Cu1.85S, and occasion revision of existing phase diagrams. All transitions are characterized by hysteresis in the attainment of equilibrium and a greater or lesser dependence on thermal history and/or thermal recycling. Thermodynamic functions have been evaluated and selected values are, for R = 8.3144 J[middle dot]K-1[middle dot]mol-1:en_US
dc.format.extent61242 bytes
dc.format.extent3118 bytes
dc.format.extent1288987 bytes
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dc.format.mimetypeapplication/pdf
dc.language.isoen_USen_US
dc.publisherElsevieren_US
dc.titleThermodynamics of copper sulfides III. Heat capacities and thermodynamic properties of Cu1.75S, Cu1.80S, and Cu1.85S from 5 to about 700 Ken_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of? Chemistry. University of Michigan, Ann Arbor, Michigan 48109. U.S.A.en_US
dc.contributor.affiliationumDepartment of? Chemistry. University of Michigan, Ann Arbor, Michigan 48109. U.S.A.en_US
dc.contributor.affiliationotherDepartment of Chemistry, University of Oslo, Blindern. 0315 Oslo 3, Norwayen_US
dc.contributor.affiliationotherDepartment of Chemistry, University of Oslo, Blindern. 0315 Oslo 3, Norwayen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/27005/3/0000572.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0021-9614(87)90008-5en_US
dc.identifier.sourceThe Journal of Chemical Thermodynamicsen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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