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Structural characterization of the sulfur-capped triangulo cluster, Cp2W2Fe(CO)7(S)

dc.contributor.authorDouglas Williams, P.en_US
dc.contributor.authorDavid Curtis, M.en_US
dc.date.accessioned2006-04-07T20:11:52Z
dc.date.available2006-04-07T20:11:52Z
dc.date.issued1988-09-06en_US
dc.identifier.citationDouglas Williams, P., David Curtis,, M. (1988/09/06)."Structural characterization of the sulfur-capped triangulo cluster, Cp2W2Fe(CO)7(S)." Journal of Organometallic Chemistry 352(1-2): 169-176. <http://hdl.handle.net/2027.42/27140>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-42V1VBR-W9/2/278be509bcefcfe346982686bd37b118en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/27140
dc.description.abstractCp2W2(CO)4(W[triple bond]) reacts with Fe2(CO)6([mu]-S2) to give Cp2W2Fe(CO)7([mu]3-S) (1) (10%) and Cp2W2Fe2(CO)8([mu]3-S)2 (5%). Spectral properties, cyclic voltammetry, and the structure of 1 are reported. Cluster 1 is a triangulo cluster [CpW(CO)2]2(Fe(CO)3)([mu]3-S), with bond lengths: W-W 3.036(1) A, W-Fe 2.80(2) (avg.) W-S 2.36(1) A, and Fe-S 2.204(7) A. Crystallographic data: a, b, c 16.212(4), 12.657(6), 20.236(8) A; [beta] 113.25(3)[deg]; V 3815(2) A3; Z = 8; [varrho]c 2.72 g/cm3; R1 = 0.070; R2 = 0.10 on 4060 reflections. A qualitative EHMO scheme is used to rationalize the lack of contraction of the metal-metal bonds which is usually observed when such bonds support bridging sulfide ligands.en_US
dc.format.extent625347 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleStructural characterization of the sulfur-capped triangulo cluster, Cp2W2Fe(CO)7(S)en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/27140/1/0000133.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-328X(88)83031-6en_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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