Structural characterization of the sulfur-capped triangulo cluster, Cp2W2Fe(CO)7(S)
dc.contributor.author | Douglas Williams, P. | en_US |
dc.contributor.author | David Curtis, M. | en_US |
dc.date.accessioned | 2006-04-07T20:11:52Z | |
dc.date.available | 2006-04-07T20:11:52Z | |
dc.date.issued | 1988-09-06 | en_US |
dc.identifier.citation | Douglas Williams, P., David Curtis,, M. (1988/09/06)."Structural characterization of the sulfur-capped triangulo cluster, Cp2W2Fe(CO)7(S)." Journal of Organometallic Chemistry 352(1-2): 169-176. <http://hdl.handle.net/2027.42/27140> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TGW-42V1VBR-W9/2/278be509bcefcfe346982686bd37b118 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/27140 | |
dc.description.abstract | Cp2W2(CO)4(W[triple bond]) reacts with Fe2(CO)6([mu]-S2) to give Cp2W2Fe(CO)7([mu]3-S) (1) (10%) and Cp2W2Fe2(CO)8([mu]3-S)2 (5%). Spectral properties, cyclic voltammetry, and the structure of 1 are reported. Cluster 1 is a triangulo cluster [CpW(CO)2]2(Fe(CO)3)([mu]3-S), with bond lengths: W-W 3.036(1) A, W-Fe 2.80(2) (avg.) W-S 2.36(1) A, and Fe-S 2.204(7) A. Crystallographic data: a, b, c 16.212(4), 12.657(6), 20.236(8) A; [beta] 113.25(3)[deg]; V 3815(2) A3; Z = 8; [varrho]c 2.72 g/cm3; R1 = 0.070; R2 = 0.10 on 4060 reflections. A qualitative EHMO scheme is used to rationalize the lack of contraction of the metal-metal bonds which is usually observed when such bonds support bridging sulfide ligands. | en_US |
dc.format.extent | 625347 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Structural characterization of the sulfur-capped triangulo cluster, Cp2W2Fe(CO)7(S) | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055 U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055 U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/27140/1/0000133.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0022-328X(88)83031-6 | en_US |
dc.identifier.source | Journal of Organometallic Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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