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A Mild Oxidation of 1.1 - Diorganometallics to Ketones and Aldehydes. A New Stereoselective Aunroach to Aldol products - Part 1
dc.contributor.authorKnochel, Paulen_US
dc.contributor.authorXiao, Chaodongen_US
dc.contributor.authorYeh, Ming Chang P.en_US
dc.date.accessioned2006-04-07T20:34:31Z
dc.date.available2006-04-07T20:34:31Z
dc.date.issued1988en_US
dc.identifier.citationKnochel,, Paul, Xiao, Chaodong, Yeh, Ming Chang P. (1988)."." Tetrahedron Letters 29(51): 6697-6700. <http://hdl.handle.net/2027.42/27621>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-42HPFMY-CC/2/d10abc2aa52514e21d0e03e4235c5445en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/27621
dc.description.abstractThe 1,1-diorganometallics of magnesium and zinc 1 are converted by the reaction with Me3SnCl to the 1,1-diorganometallics of tin and zinc 2 which are readily oxidized by dry air at -10[deg] to 0[deg]C to afford the corresponding aldehydes and ketones 3 in 57-91% yield. This mild oxidation reaction allows a new stereoselective approach to aldol products. An extension of the reaction to 1,1-diorganometallics of silicon and zinc is described.en_US
dc.format.extent215093 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleA Mild Oxidation of 1.1 - Diorganometallics to Ketones and Aldehydes. A New Stereoselective Aunroach to Aldol products - Part 1en_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/27621/1/0000665.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0040-4039(00)82431-4en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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