Sulfite-sensitive solvent/polymeric-membrane electrode based on bis(diethyldithiocarbamato)mercury(II)
dc.contributor.author | Pranitis, David M. | en_US |
dc.contributor.author | Meyerhoff, Mark E. | en_US |
dc.date.accessioned | 2006-04-07T20:56:49Z | |
dc.date.available | 2006-04-07T20:56:49Z | |
dc.date.issued | 1989 | en_US |
dc.identifier.citation | Pranitis, David M., Meyerhoff, Mark E. (1989)."Sulfite-sensitive solvent/polymeric-membrane electrode based on bis(diethyldithiocarbamato)mercury(II)." Analytica Chimica Acta 217(): 123-133. <http://hdl.handle.net/2027.42/28138> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6TF4-44Y680V-M4/2/30d93a65be2878929d2b522e34d87606 | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/28138 | |
dc.description.abstract | A new solvent/polymeric-membrane electrode which exhibits significant potentiometric response toward sulfite ion in the 1 x 10-6-1 x 10-3 M range is described. The membrane is prepared by incorporation of neutral bis(diethyldithiocarbamato)mercury (II) in a thin film of plasticized poly (vinyl chloride). In sharp contrast to classical Hofmeister behavior, the resulting membrane displays little or no response to a wide range of anions (log Kpoti,j [les] -4, i being sulfite) including sulfate, nitrate, nitrite, chloride, perchlorate, salicylate, and alkylsulfonates. Bromide and thiocyanate are moderate interferents, while significant response to iodide, thiosulfate, and sulfide is observed. These selectivity data, along with other response characteristics of the membrane, are used to postulate the mechanism by which the electrode responds to sulfite. Preliminary studies demonstrate that the electrode can be used in conjunction with an outer gas-permeable membrane for highly selective detection of total sulfite species in the form of sulfur dioxide. | en_US |
dc.format.extent | 750941 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Sulfite-sensitive solvent/polymeric-membrane electrode based on bis(diethyldithiocarbamato)mercury(II) | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/28138/1/0000589.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/S0003-2670(00)80392-X | en_US |
dc.identifier.source | Analytica Chimica Acta | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
Files in this item
Remediation of Harmful Language
The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.
Accessibility
If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.