Thermodynamics of thallium alkanoates VI. Thallium(I) n-heptanoate revisited
dc.contributor.author | Labban, Abdul K. | en_US |
dc.contributor.author | Lopez de la Fuente, F. L. | en_US |
dc.contributor.author | Cheda, Jose A. R. | en_US |
dc.contributor.author | Westrum, Jr. , Edgar F. | en_US |
dc.contributor.author | Fernandez-Martin, F. | en_US |
dc.date.accessioned | 2006-04-07T20:58:42Z | |
dc.date.available | 2006-04-07T20:58:42Z | |
dc.date.issued | 1989-04 | en_US |
dc.identifier.citation | Labban, A. K., Lopez de la Fuente, F. L., Cheda, J. A. R., Westrum, Jr., Edgar F., Fernandez-Martin, F. (1989/04)."Thermodynamics of thallium alkanoates VI. Thallium(I) n-heptanoate revisited." The Journal of Chemical Thermodynamics 21(4): 375-384. <http://hdl.handle.net/2027.42/28189> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WHM-4CRHC6N-X9/2/749b801d3eef652f7417a6578f7d641e | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/28189 | |
dc.description.abstract | The heat capacity of thallium(I) n-heptanoate has been remeasured on a new sample on which the preparative procedures were modified to eliminate the 1-1 (salt+acid) complex (soap) in a previously studied sample. The sub-ambient heat capacity of a new highly pure thallium(I) n-heptanoate is characterized by one set of transitions between 262 and 272 K and another transition at 301 K. The lowest transition temperature at 262.1 K has a maximum of Cp, m [approximate] 559R. Next, a bifurcated pair (at 268.6 and 271.4K) have Cp, m [approximate] 300R, and the highest transition (at 301.0 K) has a maximum Cp, m [approximate] 1697R. The corresponding values of [Delta]trsSmo for the two sets are about 2.24R and 1.10R. At 298.15 K the values of [Delta]0TSmo, [Delta]0THmo, and [Phi]mo(T) are 39.79R, 5979R[middle dot]K, and 19.74R. Smoothed thermodynamic functions at selected temperatures are tabulated through melting. | en_US |
dc.format.extent | 598149 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | Thermodynamics of thallium alkanoates VI. Thallium(I) n-heptanoate revisited | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbsecondlevel | Biological Chemistry | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Health Sciences | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.contributor.affiliationum | Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, U.S.A. | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/28189/1/0000641.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0021-9614(89)90138-9 | en_US |
dc.identifier.source | The Journal of Chemical Thermodynamics | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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