View Item 

Show simple item record

Synthesis and reactivity of open-chain and cyclic 2-cyano zinc and copper organometallics
dc.contributor.authorMajid, Tahir N.en_US
dc.contributor.authorYeh, Ming Chang P.en_US
dc.contributor.authorKnochel, Paulen_US
dc.date.accessioned2006-04-07T21:01:14Z
dc.date.available2006-04-07T21:01:14Z
dc.date.issued1989en_US
dc.identifier.citationMajid, Tahir N., Yeh, Ming Chang P., Knochel,, Paul (1989)."Synthesis and reactivity of open-chain and cyclic 2-cyano zinc and copper organometallics." Tetrahedron Letters 30(38): 5069-5072. <http://hdl.handle.net/2027.42/28256>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-42HFVS6-F0/2/361dbbafadc4c51cc4621dbc616e6c0cen_US
dc.identifier.urihttps://hdl.handle.net/2027.42/28256
dc.description.abstractVarious open-chain and cyclic [beta]-cyano zinc and copper organometallics can be prepared by the reaction of the corresponding organic halides with zinc and subsequent transmetalation with CuCN [middle dot] 2 LiCl. They react in fair to good yields with various organic electrophiles (enones, allylic bromides and benzoyl chloride) affording highly functionalized nitriles. High diastereoselectivities have been observed in coupling reactions with the cyclic 2-cyano organocopper derivatives. The x-ray structure of cyanoethylzinc iodide is also reported.en_US
dc.format.extent303891 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleSynthesis and reactivity of open-chain and cyclic 2-cyano zinc and copper organometallicsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 USAen_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/28256/1/0000709.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0040-4039(01)93449-5en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


Files in this item

Name:
0000709.pdf
Size:
296.7KB
Format:
PDF
View/Open

Show simple item record

Remediation of Harmful Language

The University of Michigan Library aims to describe library materials in a way that respects the people and communities who create, use, and are represented in our collections. Report harmful or offensive language in catalog records, finding aids, or elsewhere in our collections anonymously through our metadata feedback form. More information at Remediation of Harmful Language.

Accessibility

If you are unable to use this file in its current format, please select the Contact Us link and we can modify it to make it more accessible to you.