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Vibrational analysis of interfacial phosphate equilibria

dc.contributor.authorPaulissen, Vicki Bergeren_US
dc.contributor.authorKorzeniewski, Carolen_US
dc.date.accessioned2006-04-10T13:36:52Z
dc.date.available2006-04-10T13:36:52Z
dc.date.issued1990-09-10en_US
dc.identifier.citationPaulissen, Vicki Berger, Korzeniewski, Carol (1990/09/10)."Vibrational analysis of interfacial phosphate equilibria." Journal of Electroanalytical Chemistry 290(1-2): 181-189. <http://hdl.handle.net/2027.42/28390>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGB-44XMMW9-7C/2/4d852d8c3784dc9033dd12d51ec3ecb7en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/28390
dc.description.abstractPotential dependent changes in pH were observed at the platinum/solution interface by monitoring changes in the equilibrium concentration of phosphates using infrared spectroscopy. The pH at the platinum/solution interface was observed to decrease with increasing positive potentials in alkaline solutions. At potentials in the oxide region of platinum, changes in the composition of bulk solution arise owing to the formation of surface oxides. The potential dependent pH changes observed in these studies are consistent with theories concerning the interfacial properties of hydrogen adsorbing metals. Such potential dependent pH changes may have important consequences when studying the electrochemical reactivity of compounds which are sensitive to pH.en_US
dc.format.extent512769 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleVibrational analysis of interfacial phosphate equilibriaen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109 U.S.A.en_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/28390/1/0000164.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-0728(90)87429-Nen_US
dc.identifier.sourceJournal of Electroanalytical Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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