A microstructural investigation of model solid state hydrodesulfurization catalysts
dc.contributor.author | Sachdev, Amit | en_US |
dc.contributor.author | Lindner, James | en_US |
dc.contributor.author | Schwank, Johannes W. | en_US |
dc.contributor.author | Garcia, Maria A. Villa | en_US |
dc.date.accessioned | 2006-04-10T13:39:15Z | |
dc.date.available | 2006-04-10T13:39:15Z | |
dc.date.issued | 1990-08 | en_US |
dc.identifier.citation | Sachdev, Amit, Lindner, James, Schwank, Johannes, Garcia, Maria A. Villa (1990/08)."A microstructural investigation of model solid state hydrodesulfurization catalysts." Journal of Solid State Chemistry 87(2): 378-395. <http://hdl.handle.net/2027.42/28450> | en_US |
dc.identifier.uri | http://www.sciencedirect.com/science/article/B6WM2-4B6NXBD-R5/2/2f807b9826271d3703466c27ccaf0ada | en_US |
dc.identifier.uri | https://hdl.handle.net/2027.42/28450 | |
dc.description.abstract | Model molybdenum disulfide-based solid state synthesis catalysts have been prepared and tested catalytically in the HDS of thiophene. Both promoted and sulfur-deficient samples were prepared and the kinetic analyses were done at temperatures ranging from 473-673 K and atmospheric pressure. Structural characterization was carried out using X-ray diffraction and analytical and high resolution electron microscopy. The results indicate that the active catalysts possess a high degree of disorder in the directions, which represent the edges of the MoS2 crystal. This work also establishes that both Group VIII promotion and sulfur deficiency lead to similar structural changes in the molybdenum sulfide lattice of this specific solid state system. These structural traits can be correlated with increased HDS activity. | en_US |
dc.format.extent | 17059134 bytes | |
dc.format.extent | 3118 bytes | |
dc.format.mimetype | application/pdf | |
dc.format.mimetype | text/plain | |
dc.language.iso | en_US | |
dc.publisher | Elsevier | en_US |
dc.title | A microstructural investigation of model solid state hydrodesulfurization catalysts | en_US |
dc.type | Article | en_US |
dc.rights.robots | IndexNoFollow | en_US |
dc.subject.hlbsecondlevel | Materials Science and Engineering | en_US |
dc.subject.hlbsecondlevel | Chemistry | en_US |
dc.subject.hlbsecondlevel | Chemical Engineering | en_US |
dc.subject.hlbtoplevel | Science | en_US |
dc.subject.hlbtoplevel | Engineering | en_US |
dc.description.peerreviewed | Peer Reviewed | en_US |
dc.contributor.affiliationum | Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136, USA | en_US |
dc.contributor.affiliationum | epartment of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136, USA | en_US |
dc.contributor.affiliationum | epartment of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136, USA | en_US |
dc.contributor.affiliationother | epartamento de Química Organometálica, Facultad de Química, Universidad de Oviedo, Oviedo-33071, Spain | en_US |
dc.description.bitstreamurl | http://deepblue.lib.umich.edu/bitstream/2027.42/28450/1/0000239.pdf | en_US |
dc.identifier.doi | http://dx.doi.org/10.1016/0022-4596(90)90040-5 | en_US |
dc.identifier.source | Journal of Solid State Chemistry | en_US |
dc.owningcollname | Interdisciplinary and Peer-Reviewed |
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