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Synthesis and reactivity of rhodium(I) and iridium(I) complexes of the dianions of 2,3-pyrazinedicarboxylic and 2,5-pyrazinedicarboxylic acid
dc.contributor.authorBayon, Joan Carlesen_US
dc.contributor.authorNet, G.en_US
dc.contributor.authorReal, J.en_US
dc.contributor.authorRasmussen, Paul G.en_US
dc.date.accessioned2006-04-10T13:47:54Z
dc.date.available2006-04-10T13:47:54Z
dc.date.issued1990-03-27en_US
dc.identifier.citationBayon,, J. C., Net, G., Real, J., Rasmussen,, P. G. (1990/03/27)."Synthesis and reactivity of rhodium(I) and iridium(I) complexes of the dianions of 2,3-pyrazinedicarboxylic and 2,5-pyrazinedicarboxylic acid." Journal of Organometallic Chemistry 385(3): 409-415. <http://hdl.handle.net/2027.42/28667>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6TGW-42V1PJ0-12N/2/d8b1ed2dfcbe6d2a8bdfb964d0fdc429en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/28667
dc.description.abstractRhodium and iridium complexes of the title ligands have been prepared containing cyclooctadiene, carbonyl, phosphine and phosphite ancillary ligands. The complexes are mononuclear or dinuclear depending on the method of preparation and the leaving group basicity. The geometries of the complexes derived from the 2,3- and 2,5-dianions show marked differences owing to differences in the steric interaction between the carboxyl groups. Clear structural assignments were made possible by the symmetry requirements revealed by the infrared and NMR spectra.en_US
dc.format.extent538057 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleSynthesis and reactivity of rhodium(I) and iridium(I) complexes of the dianions of 2,3-pyrazinedicarboxylic and 2,5-pyrazinedicarboxylic aciden_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDepartment of Chemistry, The University of Michigan, Ann Arbor, MI 48109 U.S.A.en_US
dc.contributor.affiliationotherDepartament de Química, Universitat Autònoma de Barcelona, Bellaterra, 08193 Barcelona, Spainen_US
dc.contributor.affiliationotherDepartament de Química, Universitat Autònoma de Barcelona, Bellaterra, 08193 Barcelona, Spainen_US
dc.contributor.affiliationotherDepartament de Química, Universitat Autònoma de Barcelona, Bellaterra, 08193 Barcelona, Spainen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/28667/1/0000484.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/0022-328X(90)85012-Nen_US
dc.identifier.sourceJournal of Organometallic Chemistryen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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