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1,2-Addition of dimethyl(phenyl)silyllithium to cyclic [alpha],[beta]-unsaturated ketones and regiospecific generation of cyclic silyl enol ethers through brook rearrangement of the 1,2-addition products

dc.contributor.authorKoreeda, Masatoen_US
dc.contributor.authorKoo, Sanghoen_US
dc.date.accessioned2006-04-10T13:57:58Z
dc.date.available2006-04-10T13:57:58Z
dc.date.issued1990en_US
dc.identifier.citationKoreeda,, Masato, Koo, Sangho (1990)."1,2-Addition of dimethyl(phenyl)silyllithium to cyclic [alpha],[beta]-unsaturated ketones and regiospecific generation of cyclic silyl enol ethers through brook rearrangement of the 1,2-addition products." Tetrahedron Letters 31(6): 831-834. <http://hdl.handle.net/2027.42/28922>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-42H2C41-1TG/2/039b5f274b4b2fa76fc188e1f8e829ffen_US
dc.identifier.urihttps://hdl.handle.net/2027.42/28922
dc.description.abstractA highly convenient two-step sequence for the regiospecific synthesis of cyclic silyl enol ethers has been developed involving the 1,2-addition of dimethyl(phenyl)silyllithium to cyclic [alpha],[beta]-unsaturated ketones followed by the treatment of the resulting silyl carbinols with a catalytic amount of NaH in THF at 25 [deg]C.en_US
dc.format.extent281929 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.title1,2-Addition of dimethyl(phenyl)silyllithium to cyclic [alpha],[beta]-unsaturated ketones and regiospecific generation of cyclic silyl enol ethers through brook rearrangement of the 1,2-addition productsen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumDeparment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 USAen_US
dc.contributor.affiliationumDeparment of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109 USAen_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/28922/1/0000759.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0040-4039(00)94639-2en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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