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SN2' Substitutions of 1,3-Dichloropropenes with the Functionalized Copper-Zinc Reagents RCu(CN)ZnX
dc.contributor.authorHuai Gu Chen,en_US
dc.contributor.authorGage, Jennifer L.en_US
dc.contributor.authorBarrett, Stephen D.en_US
dc.contributor.authorKnochel, Paulen_US
dc.date.accessioned2006-04-10T13:59:25Z
dc.date.available2006-04-10T13:59:25Z
dc.date.issued1990en_US
dc.identifier.citationHuai Gu Chen, , Gage, Jennifer L., Barrett, Stephen D., Knochel,, Paul (1990)."SN2' Substitutions of 1,3-Dichloropropenes with the Functionalized Copper-Zinc Reagents RCu(CN)ZnX." Tetrahedron Letters 31(13): 1829-1832. <http://hdl.handle.net/2027.42/28958>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-42H2DTW-2BK/2/21d38ecd73a5bf53e53924951710b168en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/28958
dc.description.abstractThe addition of benzenesulfenyl (or benzeneselenyl) chlorides to propargylic chlorides affords regio- and stereospecifically (E)-1,3-dichloro-2-phenylsulfenyl (or phenylselenyl) propenes (2a-c). These new reagents were found to react with excellent SN2' selectivity with the highly functionalized copper-zinc reagents RCu(CN)ZnX, affording polyfunctional vinylic-thioethers or -selenides of type 3. The acidic hydrolysis of 3 furnishes symmetrical ketones in good yields.en_US
dc.format.extent231389 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titleSN2' Substitutions of 1,3-Dichloropropenes with the Functionalized Copper-Zinc Reagents RCu(CN)ZnXen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.en_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.en_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.en_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan, Ann Arbor, Michigan, 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/28958/1/0000795.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0040-4039(00)98797-5en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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