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Preparation of functionalized zinc and copper organometallics containing sulfur functionalities at the alpha or gamma position
dc.contributor.authorAchyutha Rao, Siddurien_US
dc.contributor.authorTucker, Charles E.en_US
dc.contributor.authorKnochel, Paulen_US
dc.date.accessioned2006-04-10T13:59:53Z
dc.date.available2006-04-10T13:59:53Z
dc.date.issued1990en_US
dc.identifier.citationAchyuthaRao, Sidduri, Tucker, Charles E., Knochel,, Paul (1990)."Preparation of functionalized zinc and copper organometallics containing sulfur functionalities at the alpha or gamma position." Tetrahedron Letters 31(52): 7575-7578. <http://hdl.handle.net/2027.42/28970>en_US
dc.identifier.urihttp://www.sciencedirect.com/science/article/B6THS-4325SPF-42/2/ce0c81ce72b962832b3e3fe307f7dff1en_US
dc.identifier.urihttps://hdl.handle.net/2027.42/28970
dc.description.abstract[alpha]-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 [deg]C (0.5-2 h), affording sulfur stabilized organozinc derivatives of type 2. The presence of a functional group such as an ester or a cyano group is tolerated in these organometallics. After a transmetallation to the corresponding copper reagent 3, they react with a wide range of electrophiles. Zinc and copper organometallics bearing a thiophenyl or a phenylsulfinyl group at the [gamma]-position have also been prepared showing the generality of our approach.en_US
dc.format.extent288769 bytes
dc.format.extent3118 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypetext/plain
dc.language.isoen_US
dc.publisherElsevieren_US
dc.titlePreparation of functionalized zinc and copper organometallics containing sulfur functionalities at the alpha or gamma positionen_US
dc.typeArticleen_US
dc.rights.robotsIndexNoFollowen_US
dc.subject.hlbsecondlevelMaterials Science and Engineeringen_US
dc.subject.hlbsecondlevelChemistryen_US
dc.subject.hlbsecondlevelChemical Engineeringen_US
dc.subject.hlbsecondlevelBiological Chemistryen_US
dc.subject.hlbtoplevelEngineeringen_US
dc.subject.hlbtoplevelScienceen_US
dc.subject.hlbtoplevelHealth Sciencesen_US
dc.description.peerreviewedPeer Revieweden_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan Ann Arbor, Michigan 48109 U.S.A.en_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan Ann Arbor, Michigan 48109 U.S.A.en_US
dc.contributor.affiliationumThe Willard H. Dow Laboratories, Department of Chemistry, The University of Michigan Ann Arbor, Michigan 48109 U.S.A.en_US
dc.description.bitstreamurlhttp://deepblue.lib.umich.edu/bitstream/2027.42/28970/1/0000807.pdfen_US
dc.identifier.doihttp://dx.doi.org/10.1016/S0040-4039(00)97302-7en_US
dc.identifier.sourceTetrahedron Lettersen_US
dc.owningcollnameInterdisciplinary and Peer-Reviewed


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